Journal Articles (before-1995): Recent submissions

  • Measurement of Coagulation Forces by Ultracentrifugation 
    Melville, J. B.; Willis, E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (3), 1972)
    A technique, using an ultracentrifuge, has been developed to measure forces of coagulation of colloidal sols. Such measurements are appropriate for the study of sols stabilized by adsorbed long chain molecules where classical ...
  • Solubilization of p-Xylenc in Sodium Dodecyl Sulphate Micelles 
    Fox, K. K.; Robb, I. D.; Smith, R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (3), 1972)
    The solubilization of p-xylcnc in SDS micelles has been studied by an n.m.r. technique utilizing the line broadening caused by paramagnetic counterions. It was found that the p-xylenc cannot be considered to be solubilized ...
  • Kinetics of the Oxidation of Formic Acid by Aquomangancse(III) Ions in Aqueous Perchlorate Media 
    Wells, C. F.; Whatley, D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (3), 1972)
    The kinetics of the slow oxidation of formic acid by aquomangancsc(IIl) ions in aqueous perchlorate media show that intermediate complexes arc present; three complexes arc postulated to explain the variation of rate with ...
  • Crystal Growth in Manganese-Doped Magnesium Oxide Powders 
    Guilliatt, I. F.; Brett, N. H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (3), 1972)
    The crystallite size of pure and Mn-dopcd MgO has been measured after calcination at different temperatures in oxidizing and reducing atmospheres. The oxidation state and location of the impurity ions was assessed by e.s.r. ...
  • Kinetics of Anionic Polymerizations of Styrene and Its m- and p-Derivatives: Hammett’s Relations 
    Hirohara, Hideo; Nakayama, Masatoshi; Ise, Norio (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (1), 1972)
    The kinetics of anionic polymerizations of styrene, m-methylstyrene, p-isopropylstyrene, and p-methylstyrene were investigated in tetrahydrofuran (THF) at 25°C with Cs+ as gegenion in the presence and absence of an electric ...
  • Unstable Intermediates Part 107.—Radiation Damage Products in Choline Chloride 1 
    Symons, M C R (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (2), 1972)
    At 77 K the major radicals detected by e.s.r. in y-irradiated cholinechloride [Mc3N4CH2CH2OHCI ] are CH2CH2OH, as previously suggested, and a species containing one hydrogen and one chlorine atom, closely resembling C1OH“. ...
  • Reactions of Group 3 Metal Alkyls in the Gas Phase*: Part 8.—Homogeneous Thermal Unimolecular Elimination of Ethylene from Triethylaluminium 
    Cocks, Alan T.; Egger, Kurt W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (3), 1972)
    The kinetics of the homogeneous gas-phase elimination of ethylene from triethylaluminium have been studied in the presence of excess propene in the temperature range 426-488 K. The observed first-order rate constants based ...
  • Chemisorption of Hydrogen on Evaporated Copper Films 
    Alexander, C S; Pritchard, J (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (2), 1972)
    Surface potentials (s.p.) of atomic hydrogen adsorbed at low temperatures on clean copper films show wide variations from one film to another. This is believed to reflect varying proportions of different crystal planes. ...
  • Kinetics of Anionic Polymerization of o-Methylstyrene in 2-Methyltetrahydrofuran and Tetrahydrofuran 
    Hirohara, Hideo; Nakayama, Masatoshi; Kawabata, Ryoichi; Ise, Norio (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (1), 1972)
    The kinetics of anionic polymerization of o-methylstyrene were investigated in 2-methyltetrahydrofuran (MTHF) at 25°C with Li+, Na+, K+ and Cs+ as gegenions in the presence and absence of an electric field. Conductance ...
  • Infra-red Studies of Reactions on Oxide Surfaces: Part 1.— Boron Trifluoride on Silica 
    Morrow, B. A.; Devi, A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (3), 1972)
    Infra-red spectroscopy has been used to study the adsorption of boron trifluoride on silica. On highly dehydroxylatcd samples chemisorption is rapid and the major product initially appears to be a surface SiOBF2 species. ...
  • Infra-red Studies of Carboxylic Acid Vapours Adsorbed on Evaporated Germanium Films 
    Howe, R. F.; Metcalfe, A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (3), 1972)
    An experimental method has been developed for the observation of infra-red spectra of molecules adsorbed on germanium surfaces. The interactions of formic, acetic and propionic acids with germanium surfaces have been ...
  • Dissociation Equilibrium of Nitroform in Polar Solvents Studied by Pulse Radiolysis 
    Chaudhri, Shamim A.; Asmus, K. D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (3), 1972)
    The dissociation equilibrium C(NO2)3H --- C(NO2)3+Hsol and the related kinetics have been studied for various solvents (alcohols, acetone, and water) by means of pulse radiolysis. Nitroform anions were produced by ...
  • Lattice Defects in Plastic Organic Crystals: Part 7.—Isotope Mass Effects in Self-diffusion in Cyclohexane 
    Chadwick, A. V.; Sherwood, J. N. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (1), 1972)
    A study has been made of the diffusion of the species 12C514C11H12 and 12C62H113H1 in single crystals of cyclohexane at 242 K. The measured diffusion coefficients are in good agreement with previously published values. An ...
  • Infra-Red Study of the Adsorption of Ammonia on MgO: Part 2.—The Hydrated Surface 
    Tench, A J (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (2), 1972)
    Ammonia is weakly adsorbed on hydrated MgO by hydrogen-bonding of the nitrogen to hydroxyl groups exposed on the surface and a strong band at 3045 cm-1 is attributed to surface hydroxyl groups perturbed by the adsorbed ...
  • Infra-Red Study of the Adsorption of Ammonia on MgO: Part 1.—The Dehydrated Surface 
    Tench, A J; Giles, D (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (2), 1972)
    The adsorption of ammonia gas has been studied on dehydrated MgO. The symmetrical bending vibration v2 of ammonia is considerably perturbed by the presence of the surface and a doubling of this band is observed at low ...
  • Electrical Conduction in Ammonium Perchlorate 
    Owen, G. P.; Thomas, J. M.; Williams, J. O. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (12), 1972)
    D.c. along with a few a.c. electrical measurements are reported for ammonium perchlorate (AP) in compressed disc and single crystal form. The near-identity of the electrical conductivity of AP to that of certain other ...
  • Heats of Dilution of Sub-micellar Aqueous Surfactant Solutions 
    Birch, B. J.; Hall, D. G. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (12), 1972)
    Heats of dilution of sub-micellar solutions of a series of sodium alkyl sulphates and alkyltrimethylammonium bromides are reported and two possible interpretations of the observed deviations from simple Debye-Hiickel theory ...
  • Phase Diagram and Thermodynamic Data for the Hydrogen/Vanadium System 
    Griffiths, R.; Pryde, J. A.; Righini-Brand, A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (12), 1972)
    Ultra-high vacuum techniques have been used to investigate the hydrogen/vanadium system in the pressure, temperature and concentration ranges 10-7-10Torr (1 Torr= 133.32 Nm~2), 260-460 K, and H/V = 0-0.85 (concentrations ...
  • Transition State Theory of Zeolitic Diffusion: Diffusion of CH4 and CF4 in 5A Zeolite 
    Ruthven, D. M.; Derrah, R. I. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (12), 1972)
    A simple theory of zeolitic diffusion is developed from the principles of transition state theory. General expressions for the diffusivity are derived in terms of the lattice parameter and the partition function for the ...
  • Conductance Study on the Association Behaviour of Quaternary Ammonium Salts in Hydrogen-bonding Solvents 
    Goffredi, M.; Triolo, R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (12), 1972)
    Conductance measurements have been carried out at 25°C on the following systems: tctrabutyland tetrahexyl-ammonium perchlorates in methanol 4- dioxan mixtures, and tetrabutylammonium perchlorate in acetonitrile4- dioxan ...

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