The kinetics of the electrodeposition of ruthenium on vitreous carbon and the accompanying hydrogen evolution reaction has been investigated. Two mechanisms are proposed for the electrocrystallization of growth centres of ...

Kinetic equations are derived for a model in which the probability of reaction involving a particular pair of polymer substituents depends on whether none, one or two of the adjacent pairs have already reacted. The extent ...

The temperature-jump relaxation method has been used to measure the rate constants and activation parameters for the formation and the dissociation of the 1 : 1 complex between magnesium and 5-nitrosalicylic acid (nsa) and ...

Adsorption isotherms on Graphon have been obtained for a scries of n-alkanes from C5 to Ci2- Isosteric heats of adsorption as a function of fractional surface coverage were calculated for the members C6> C7 and C8. Areas ...

The heats of combustion of the gaseous alkanes, Ct to C4, have been measured at 25°C and 1 atm pressure using a flame calorimeter. A/7c°(methane, g) = -890.71 ±0.38 kJ mol-1 △^(ethane, g) = -1560.69 ±0.25 kJ mol-1 △^(propane, ...

A polystyrene latex, containing particles with a carboxylated surface, has been used as a model system for measurement of the adsorption of the n-alkanols, methanol, ethanol, propanol and butanol. Complementary measurements ...

The interaction of H2S, H2Sc, AsH3, HC1, SO2, CS2 and N2O with evaporated films of copper has been studied in the temperature range -80 to 250 C. Weak reversible adsorption of CS> and SO2, and mainly dissociative chemisorption ...

Excess enthalpies as a function of compositions have been measured by a newly designed calorimeter for the mixtures of methylene chloride with benzene, toluene, o-, m- and p-xylene at 25 and 30°C. The excess enthalpy HE ...

The self-diffusion coefficient of liquid benzene has been measured with a modified diaphragm cell. The cell incorporates a bellows in one compartment and the technique for its use makes allowance for bulk flow effects due ...

.Study of ethane pyrolysis over the ranges 920–1040 K and 0–200 Torr in a flow system allows evaluation of Arrhenius parameters for the reactions C2H6→ 2CH3·(1), CH3·+ C2H6→ CH4+ C2H5·(2). The results obtained are, ...