Journal Articles (before-1995): Recent submissions

  • Catalytic Activity and Electron Configuration of the EDA Complexes of Phthalocyanine with Alkali Metals: Hydrogen Adsorption and the H2—D2 Exchange Reaction 
    Naito, Shuichi; Ichikawa, Masaru (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (8), 1972)
    Hydrogen adsorption and H2—D2 exchange reaction on the stoichiometric EDA (electron donor-acceptor) complexes of various phthalocyanines with alkali metals (Li, Na, K, Rb) were studied and their behaviour correlated with ...
  • Infra-red Study of the Surface Properties of Rutile: Adsorption of Ethanol, n-Butanol and n-Hexanol 
    Jackson, P; Parfitt, G D (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (8), 1972)
    The vapours of ethanol, n-butanol and n-hexanol chemisorb at room temperature on a variety of rutile surfaces. The adsorption is independent of the nature of the surface, and an estimate of the ethoxide population is 3 ...
  • Solid/Liquid Phase Equilibria and Solid Compound Formation in Mixtures of Dimethyl Sulphoxide with CC14, CHC13, and CC13CHC12 
    Goates, J. Rex; Ott, J. B.; Reeder, J.; Lamb, J. D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11), 1972)
    Solid/liquid phase diagrams have been obtained from time against temperature cooling and warming curves for the three binary systems formed from dimethyl sulphoxide (DMSO) with CCl4, CHCl3, and CCl3CHCl2. The CHCl3+ DMSO ...
  • Reaction between Ammonia and Nitrogen Dioxide 
    Bedford, G.; Thomas, J. H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11), 1972)
    The reaction between ammonia and nitrogen dioxide has been studied in the temperature range 615–660 K. The products of reaction are N2, N2O, NO and H2O. A mechanism is proposed which leads to the following parameters: ...
  • Hydrogenolysis of Saturated Hydrocarbons on Evaporated Platinum Films 
    Dowie, R. S.; Whan, D. A.; Kemball, C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11), 1972)
    The reactions of ethane, propane, n-butane, isobutanc and neopentane have been examined in the presence of deuterium on platinum films. Details of the products of exchange, hydrogenolysis and, where possible, isomerization ...
  • Adsorption of Xenon and Hydrogen Atoms and their Interaction on Silver Films 
    Knapp, A. G.; Stiddard, M. H. B. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11), 1972)
    The adsorption of xenon, hydrogen, and mixtures of xenon and hydrogen on silver films at 77 K has been investigated by measurement of surface potentials by the diode method. Average surface potentials of xenon and ...
  • Propagation of Surface Tension Changes over a Surface with Limited Area 
    Lucassen, J.; Barnes, G. T. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11), 1972)
    Surface tension changes resulting from a periodic local compression and expansion of a surface propagate over the available surface area. Whether or not the extent of deformation is uniform over the whole area is ...
  • Negative Ion Reactions in Nitrous Oxide-I-Carbon Dioxide Mixtures 
    Parkes, David A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11), 1972)
    The rate constants have been measured for the following reactions in N2O + CO2 mixtures at pressures in the Torr region, using a drift tube and mass filter: NO–+ 2CO2→ CO2·NO–+ CO2, k9= 7.5 × 10–29 cm6 molecule–2 s–1, NO–+ ...
  • Electron Attachment and Negative Ion-Molecule Reactions in Nitrous Oxide 
    Parkes, David A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11), 1972)
    The negative ions formed in N2O and N2O and N2O + O2 mixtures have been studied in the gas phase using a drift tube and mass filter. Gas pressures were in the Torr range, and reduced fields were varied between 10–17 and ...
  • Thermal Decomposition of Ethyl, Isopropyl and t-Butyl Fluorides in the Gas Phase 
    Dastoor, P. N.; Emovon, E. U. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11), 1972)
    Ethyl, isopropyl and t-butyl fluorides decompose in a flow system into hydrogen fluoride and the corresponding olefin by a predominantly molecular mechanism. The first order rate constants are given by the Arrhenius ...
  • Solubility of Cadmium Cyanide and the Formation Constants of the Cadmium-Cyanide System in Dimethylformamide at 25 C 
    Jagtiani, I. A.; Siddiqi, I. W.; Tyrrell, H. J. V. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11), 1972)
    A solubility column technique has been used to measure the solubility of cadmium cyanide in dry dimethylformamide over a range of ionic strengths. The results showed that cadmium cyanide did not behave as a completely ...
  • Interaction of Inert Gases with Ionic Melts: Solubility of He, Ar, N2, O2 and CH4 in the (Na,K)NO3 Eutectic Solvent 
    Paniccia, F.; Zambonin, P. G. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11), 1972)
    The solubility of He, Ar, N2, O2 and CH4 was determined in the (Na,K)NO3 equimolar mixture by using a high-sensitivity manometric technique. The experimental findings are in agreement with the general trends valid in the ...
  • Kinetics of the Reactions of Oxygen Atoms and Nitrogen Atoms with Sulphur Trioxide 
    Jacob, Adir; Winkler, C. A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11), 1972)
    The reaction of O atoms with SO3 yields SO2 and O2 as stable products, with a white metastable solid that condenses at –10°C (thought to be SO4) as a probable intermediate. The overall rate constants are 5 × 10–17, 7 × ...
  • Flash Photolysis of HiS 
    Langford, R B; Oldershaw, G A (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (8), 1972)
    Hydrogen atoms produced by flash photolysis of H2S are “hot” and react with CO2 by process (13). H + CO2→CO + OH, ΔH= 102 kJ mol–1(13) Flash spectroscopy has been used to determine [SH] and [S2] as functions of time ...
  • Electron Spin Resonance Studies of Photo-oxidation by Metal Ions in Rigid Media at Low Temperatures: Part 4.—Survey of Photo-oxidation by the Uranyl Ion 
    Greatorex, D.; Hill, R. J.; Kemp, T. J.; Stone, T. J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11), 1972)
    The long-standing problem of the mechanism of photo-oxidation of organic and inorganic molecules by the UO2+2 ion has been explored in some detail by the matrix isolation method, the detection of trapped substrate-derived ...
  • Oxidation of Ferrous Ions by Hydroxyl Radicals 
    Jayson, G. G.; Parsons, B. J.; Swallow, A. J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11), 1972)
    Hydroxyl radicals have been found by pulse radiolysis to oxidize hydrated ferrous to ferric ions with a rate constant of (2.3 ± 0.2)× 108 M–1 s–1. The corresponding reaction of OD radicals in D2O solution has a rate constant ...
  • Energy Partition in the Photolysis of HI and of H2S 
    Oldershaw, G. A.; Porter, D. A.; Smith, A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (12), 1972)
    Yields of nitrogen from reaction (1) were used to determine the initial kinetic energy of hydrogen atoms produced by photolysis of HI and H2S in the presence of N2O. H* + N2O->N2 + OH. (1) The results show that the ...
  • Flash Photolysis and Electron Spin Resonance Study of p-Chloranil 
    Wong, S. K.; Fabes, L.; Green, W. J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (12), 1972)
    The photochemistry of p-chloranil in dioxan and in isopropyl alcohol was re-investigated by a combination of flash-optical e.s.r.-rotating sector techniques. The transient photoradical is identified as the p-tetrachlorob ...
  • Low Temperature Parahydrogen Enrichment on Non- stoichiomctric Rutile 
    Richardson, P. C.; Rudham, R.; Tullett, A. D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (12), 1972)
    The reduction of rutile by vacuum outgassing between 450-825nC, or by hydrogen or carbon monoxide at 350 C, yields active catalysts for low temperature parahydrogen enrichment due to the presence of surface Ti3 b ions. ...
  • Dilute Aqueous Solutions of Unsymmetrical Quaternary Ammonium Iodides: Part 2.—Conductance Measurements 
    Lowe, B. M.; Rendall, H. M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (12), 1972)
    Precise conductance measurements on dilute aqueous solutions of cyclic and straight chain quaternary ammonium iodides at 298 K arc reported. The results arc analyzed with the Fuoss-Hsia and Pitts equations for A(c) and arc ...

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