Journal Articles (before-1995): Recent submissions

  • Observation of Weak Primary Minima in the Interaction of Polystyrene Particles with Nylon Fibres 
    Boughey, Marie T.; Duckworth, Ralph M.; Lips, Alexander; Smith, Alec L. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    The deposition of sub-micron polystyrene particles onto dispersed nylon fibres has been studied as a function of pH and ionic strength in the vicinity of the iso-electric point of the nylon. The presence of weak primary ...
  • Thallous Chloride-Thallous Sulphide Phase Diagram 
    Brookes, Hugh C.; Coppens, Henry J.; Pelton, Arthur D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    The phase diagram of the TlCl + Tl2S system has been determined by the method of cooling curves. Calculations of thermodynamic properties of the liquid have been made using the cryoscopic data, together with an analysis ...
  • Nature of Solutions of Water in Sulphuric Acid 
    Sioli, Giancarlo; Giuffre, Luigi; Spaziante, Placido Maria (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    Proton magnetic resonance measurements have been used to justify a proposed mechanism for the interaction of water with sulphuric acid, where the molar fraction of water is y⩽ 0.5. Three different statistical states of the ...
  • Mechanism of thermolysis of tetramethylsilane and trimethylsilane 
    Baldwin, Alan C.; Davidson, Iain M. T.; Reed, Michael D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    The thermolysis of tetramethylsilane has been studied in a pulsed stirred-flow system between 840 and 1055 K, yielding significantly different Arrhenius parameters above and below 950 K. The high temperature results relate ...
  • Partial Molar Volumes and Viscosity of Benzene Solutions of Tertiary n-Alkylammonium Picrates 
    Paljk, Špela; Klofutar, Cveto (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08), 1978)
    The densities and viscosities of tri-n-propylammonium picrate, tri-n-butylammonium picrate, tri-n-pentylammonium picrae, tri-n-hexylammonium picrate, tri-n-heptylammonium picrate, tri-n-octylammonium picrate, tri-n-decylammonium ...
  • Mechanism of Exchange in the Mnn-ATP System from Fourier Transform Nuclear Magnetic Resonance and Electron Paramagnetic Resonance Data 
    Gaggelli, Elena; Laschi, Franco; Niccolai, Neri (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08), 1978)
    Nuclear spin relaxation studies have been performed on the MnII–ATP system. Longitudinal and transverse relaxation times of water protons have been measured and their dependence upon the concentration of the ligand ...
  • Infrared Studies of Halide Ion Solvation in Methanol1 
    Strauss, Imants M.; Symons, Martyn C. R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08), 1978)
    Concentrated solutions of alkali halides in methanol at low temperature have infrared spectra in the O—H stretching region that are dominated by features assigned to solvent shared ion-pairs [graphic omitted]. Such units ...
  • Infrared Study of the Adsorption of Diketones on Silica Immersed in Carbon Tetrachloride 
    Cross, Stephen N. W.; Rochester, Colin H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08), 1978)
    The adsorption of pentan-3-one and four diketones onto silica immersed in carbon tetrachloride has been studied by infrared spectroscopy. The primary surface–adsorbate interaction for all five ketones involved the formation ...
  • Evidence for a Molecular Component in the Thermal Decomposition of Azomethane 
    Marshall, Roger M.; Page, Nicholas D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08), 1978)
    The pyrolysis of a mixture containing 0.432 % azomethane in isobutane has been investigated in the ranges 580–657 K and 50–150 Torr. The high pressure limiting value of the rate constant for CH3N2CH3→ 2CH3+ N2(1) has been ...
  • Effect of Viscosity on the Bimolecular Termination Rate Constants for Semiquinone Radicals in Solution: a Kinetic E.S.R. Study 
    Elliot, John; Egan, Karen L.; Wan, Jeffrey K. S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08), 1978)
    The Arrhenius activation energies (EA) have been determined for the near diffusion-controlled bimolecular termination reactions of some semiquinone radicals in a series of solvents. It was often found that EA was less than ...
  • Free Energies and Entropies of Transfer of Ions from Water to Methanol, Ethanol and 1-Propanol 
    Abraham, Michael H.; Danil de Namor, Angela F. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08), 1978)
    Solubilities of 30 1:1 electrolytes in 1-propanol have been determined and have been combined with association constants and corrections for activity coefficients to yield standard free energies of solution in 1-propanol ...
  • Correlation between Results of X-ray Photoelectron Spectroscopic Studies and Catalytic Behaviour of MgO 
    Vinek, Hannelore; Latzel, Johannes; Noller, Heinrich; Ebel, Maria (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08), 1978)
    Different MgO samples were investigated by means of X-ray photoelectron spectroscopy and catalytic, desorption and basicity measurements. The O 1s peak of MgO showed a shoulder (or was split into two peaks) as a function ...
  • Luminescence Excitation and De-excitation Involving One-electron Transfer Aqueous Solutions of l-Aminonaphthalene-4-(Na)sulphonate 
    Prütz, Walter A.; Land, Edward J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08), 1978)
    The radiation-induced chemiluminescence (RCL) in aqueous solutions of 1-aminonaphthalene-4-(Na)sulphonate (AnsH) predominantly involves: AnsH·++ eaq→ AnsH*. This conclusion is due to quantitative correlations found between ...
  • On the Hydrolysis of Agn, T1H, Sn111 and CuI[1 
    Asmus, Klaus-Dieter; Toffel, Peter; Bonifacio, Marija (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08), 1978)
    Using pulse radiolysis with optical, conductometric and polarographic detection it is shown that the oxidation of T1+, Ag+, Cu2 ! and Sn2 ■ by hydroxyl radicals proceeds via on OH adduct: Mc"+ + •OH Me(OH)'l+. Depending ...
  • Viscosity and Conductance Studies in Ethylene Carbonate at 40°C 
    Petrella, Giuseppe; Sacco, Antonio (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08), 1978)
    Viscometric measurements of numerous electrolytes in ethylene carbonate (EC) at 40°C are reported. B-coefficients, obtained by the Jones–Dole equation, are compared with those relative to other dipolar aprotic solvents. ...
  • Kinetic Isotope Effect in the Reaction of 4-Nitrophenylnitromethane with the Cyclic Amidine Base DBU [l,5-diazabicyclo(5,4,0)undec-5-ene] 
    Caldin, Edward F.; Rogne, Otto (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08), 1978)
    Kinetic deuterium isotope effects have been determined for the reaction of the cyclic amidine base DBU [1,5-diazabicyclo(5,4,0)undec-5-ene] with the carbon acid 4-nitrophenylnitromethane in toluene solution from –5 to ...
  • Theory of Compartmentalised Free-Radical Polymerisation Reactions Part 2. 
    Birtwistle, David T.; Blackley, David C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08), 1978)
    Explicit analytic solutions are given for nr, the number of reaction loci per unit volume containing r radicals, as a function of time, t, for the case of a seeded emulsion polymerisation in which the only significant ...
  • Relaxation Processes of Hydrogen Bonded Species in a Polystyrene Matrix 
    Shukla, Jagdish P.; Walker, Stanley; Warren, John (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08), 1978)
    Various hydrogen bonded complexes of the type N—H…N within a polystyrene matrix have been characterized by means of their Eyring energy of activation parameters. The dielectric absorption of the complexes was completely ...
  • Activity Coefficients for the System HCI+COCI2+H2O at 298.15 K Effects of Higher-order Electrostatic Terms 
    Khoo, Kean H.; Lim, Tiong-Koon; Chan, Chee-Yan (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08), 1978)
    Activity coefficients for HCl in the system HCl + CoCl2 H2O, at 298.15 K and at constant total ionic strengths of 0.1, 0.5, 1.0, 2.0 and 3.0 mol kg–1, have been measured by an e.m.f. method. The results have been treated ...
  • Fourier Transform Infrared Spectroscopy of the Zeolite NaH-Y+But-l-ene System 
    Ceckiewicz, Stanisław; Barański, Andrzej; Gałuszka, Jan (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08), 1978)
    The kinetics of transformation of but-1-ene on zeolite NaH–Y with differing degrees of Na+ ion exchange was investigated at room temperature by Fourier transform infrared spectroscopy. The process of oligomerization was ...

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