Journal Articles (before-1995): Recent submissions

  • Determination of the Active Site and Mechanism for Alkene Isomerization in Cun Exchanged Y-Type Zeolite 
    John, Christopher S.; Leach, H. Frank (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    Reactions of CD2[double bond, length as m-dash]CH—CH3, but-1-ene and 3,3-dimethylbut-1-ene have been studied over a Y-type zeolite containing ∼4 CuII per unit cell. Kinetic induction periods, associated with the generation ...
  • Enthalpies of combustion of tris-(acetylacetonato) derivatives of aluminium(III), gallium(III) and indium(III) 
    Cavell, Kingsley J; Pilcher, Geoffrey (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    The enthalpies of combustion of the following tris-(acetylacetonato) derivatives have been measured and the standard enthalpies of formation at 298.15 K derived. –ΔH°c/kJ mol–1–ΔH°f/kJ mol–1 Al(C5H7O2)3(c) 7948.4 ± 1.1 ...
  • Inoperative Protonic Sites in Highly Exchanged L-Zeolites 
    Ballivet, Danielle; Barthomeuf, Denise (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    It has been shown that highly exchanged L zeolites have hydroxyls vibrating at 3740, 3730, 3680 and 3630 cm–1 and a large number of strongly interacting hydroxyls. The structural 3630 cm–1 hydroxyls, stable under the ...
  • Thermodynamics of Liquid Mixtures of Methane and Ethene 
    Calado, Jorge C. G.; Soares, VirgIlio A. M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (09), 1977)
    The total vapour pressure of liquid mixtures of methane and ethene has been measured as a function of composition at 103.94 and 115.77 K. The results have been used to estimate the excess Gibbs energy GE at these temperatures. ...
  • Activities of Olefinic Derivatives as Components of Photoinitiating Systems based on Transition-Metal Carbonyls 
    Bamford, Clement H.; Mullik, S. U. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (09), 1977)
    The derivatives studied include carboxyl- and nitrile-substituted ethylenes, perfluoro-propylene, -butadiene, -benzene and -styrene, 1,1-difluoro-2,2-dichloroethylene and several chloroethylenes. The activity of each ...
  • Exchange of Alkylammonium Ions in the Zeolite-L 
    Vansant, Etienne F; Peeters, Guido (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    A study has been made of the ion-exchange equilibria of NH+4, CH3NH+3, C2H5NH+3, n-C3H7NH+3, n-C4H9NH+3, (CH3)2NH+2, (CH3)3NH+, (C2H5)2NH+2 and (C2H5)3NH+ by the zeolite L. None of the alkylammonium ions could effect a ...
  • Photochemistry of Michler’s Ketone in Cyclohexane and Alcohol Solvents 
    Brown, Robert G; Porter, Sir George (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    The triplet lifetime of Michler's ketone has been measured in cyclohexane, isopropanol and ethanol and has been found to vary only slightly between solvents. In the light of these results, the photoreactivity of the ketone ...
  • Interaction of Duroquinone Lowest Triplet with Amines 
    Amouyal, Edmond; Bensasson, Rene (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    The reaction of the lowest triplet of duroquinone, 3Q, with tertiary amines (triethylamine TEA, diethylaniline DEA, triphenylamine TPA) has been investigated by laser flash absorption spectroscopy in non-polar (cyclohexane ...
  • I.r. Spectroscopic Study of CO2 Adsorption onto q-Al2O3 
    Morterra, Claudio; Zecchina, Adriano; Coluccia, Salvatore; Chiorino, Anna (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    The adsorption of CO2 at room temperature onto η–Al2O3 dehydrated at various temperatures between 25 and 800°C was studied by i.r. and microgravimetric techniques. The following surface species are formed; three σ-coordinated ...
  • Oxidation of 1-Phenylethanol in the Presence of Cobalt Acetylacetonates 
    Vasvari, Gabor; Gal, Dezso (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    The oxidation of 1-phenylethanol has been investigated in the presence of Co(acac)2 and Co(acac)3. It is established that in the presence of Co(acac)2 the oxidation is preceded by the formation of a Co(acac)2—ROH complex ...
  • Absolute Rate of the Reaction of C1(2P) with Molecular Hydrogen from 200-500 K 
    Lee, Jai H.; Michael, Joe V; Payne, Walter A.; Stiee, Louis J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    Rate constants for the reaction of atomic chlorine with hydrogen have been measured from 200–500 K using the flash photolysis–resonance fluorescence technique. The rate constants obey the Arrhenius equation k=(2.66 ± 0.42)× ...
  • Infrared Study of the Adsorption of Water on to the Surface of Rutile 
    Griffiths, David M; Rochester, Colin H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    Infrared spectra of the surface of three samples of rutile which had been (a) calcined in air at 723 K and heated in oxygen at 673 K, (b) calcined in air at 973 K and heated in oxygen at 673 K, and (c) calcined in air at ...
  • Vapour Pressure of H218O Ice (—50 to 0°C) and H218O Water (0 to 170°C) 
    Jakli, Gyorgy; Staschewski, D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    The vapour pressure difference between H216O and highly enriched H218O samples was measured directly with a capacitance type differential monometer between –50 and 80°C and with a U-type mercury manometer between 80 and ...
  • Detection and Identification of Organic Radicals Produced in the Low Pressure Silent Electric Discharge by an Electron Spin Resonance Spin Trapping Technique 
    Hibbert, D. Brynn; Robertson, Andrew J. B; Perkins, M. John (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    A method is described whereby free radicals are produced in a low pressure silent electric discharge between glass surfaces and are simultaneously deposited with 2-methyl-2-nitrosopropane as a spin trap on a cold surface. ...
  • Solvation Spectra Part 52.1—The Aquation of Silver Atoms and Cations: a Radiation and Electron Spin Resonance Study 
    Brown, D. Robert; Symons, Martyn C. R (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    Exposure of a range of aqueous solutions containing AgI cations to 60Co γ-rays at 77 K gave AgII and AgO together with other paramagnetic products. The AgII centres have [graphic omitted] configurations, which means that ...
  • Proton Magnetic Resonance Investigations of Nonionic Polyoxyethylene Nonylphenol Surfactant Aggregates in Nonpolar Solvents1 
    Sheih, Pong Su; Fendler, Janos H (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    1 H n.m.r. chemical shifts of polyoxyethylene(1.5) nonylphenol (Igepal CO–210); polyoxyethylene (4) nonylphenol (Igepal CO–430); polyoxyethylene(5) nonylphenol (Igepal CO–520); polyoxyethylene(6) nonylphenol (Igepal CO–530); ...
  • Heterogeneous Structures in Promoted Chromia-PAlumina Dehydrogenation Catalysts 
    Masson, J; Bonnier, J. M (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    The catalytic activity and various physical–chemical properties (crystallographic phase, specific surface area, electric conductivity, e.p.r.) of alkali metal doped Al2O3+ Cr2O3 catalysts (7.5 mol % Cr2O3) have been compared ...
  • Solvation Spectra: Part 53—Infrared and Nuclear Magnetic Resonance Studies of the Tetrahydroborate Anion in various Pure Solvents and Binary Aqueous Mixtures 
    Strauss, Imants M.; Symons, Martyn C. R.; Thompson, Vicky K. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (09), 1977)
    Borohydride salts have been studied in various solvents by infrared and n.m.r. spectroscopy. Solutions in water containing HOD in low concentration exhibit an O—D stretching frequency profile indicative of relatively strong ...
  • Reorganisation of Nickel under Steam Reforming Conditions 
    Moayeri, Massoud; Trimm, David L. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (09), 1977)
    The reorganisation of nickel films supported on silica has been studied under conditions pertinent to the steam reforming of propylene. Examination of reorganisation under steam reforming conditions, and in the presence ...
  • Solubility of Nitric Oxide in Aqueous and Nonaqueous Solvents 
    Shaw, Anthony W.; Vosper, Alan J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (09), 1977)
    The solubility of NO in various solvents has been measured over a range of temperatures. The results are compared with the values predicted by various current theories of gas solubility.

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