Methylene Blue may be regarded as a model compound of flavin co-enzymes, and its reactions in solution are interesting from a biochemical viewpoint. The reduction of Methylene Blue by dihydro-compounds, catalyzed by aliphatic ...

νmax and εmax for the n–π* transition of acetone in aqueous solution do not vary monotonically with acetone concentration. The Klotz-Worley R parameter for these solutions shows a maximum at 0.05 x2 whereas carbonyl ...

Anthraquinone-2-sodium sulphonate in “aqueous” solutions within the range pH 14 to 100% H2SO4(and also in oleum) is both reduced and hydroxylated when irradiated with u.v. or visible light. The major hydroxy-photoproducts ...

The pyrolysis of 1-ethylcyclohexa-1,4-diene has been studied from 316 to 379°C in the gas phase at pressures of around 10 Torr. Under these conditions, in an aged reaction vessel, the reaction was strictly first order, and ...

Cryoscopic measurements have been carried out in formamide for 30 1 : 1 electrolytes in the concentration range 0.002 to 0.25 mol kg-1. Activity coefficients (y±) for all the electrolytes have been evaluated using a modified ...

An electrochemical method of determination of the activity of hydrogen ions in strongly acidic media has been developed. The novelty of the method rests in the way in which the potential of a glass electrode is measured. ...

The thermal isomerization of 3,3,4,4-tetrafluorocyclobutene has been shown to yield 1,1,4,4- tetrafluorobuta-l,3-diene quantitatively. In the temperature range 306 to 36O'C the reaction is a homogeneous first order essentially ...

The molecular sieve properties of the carbonaceous products prepared by chemical dehydrohalogenation of polyvinylidene chloride (hereafter referred to as “carbons”) have been investigated by a heat of immersion study, using ...

Irradiation of α-aminobutyric acid single crystals with 60Co γ-rays at 26 to 77 K results in the trapping of the protonated molecular-anion CH3CH2CH(NH3+)CO2H–(R1). During thermal annealing to 440 K, six further radicals ...

Diethyl succinate has been irradiated under vacuum with 60Co γ-radiation. An attempt was made to identify and measure the complete product spectrum. Twenty different products were found after a maximum total dose of 9 × ...