Journal Articles (before-1995): Recent submissions

  • Catalytic Activities of Polynaphthoquinone, Containing various Metal Halides: Dehydrogenation of Formic Acid, Cyclohexene, Ammonia and Alcohols, and Isomerization of Butene 
    Iwasawa, Yasuhiro; Soma, Mitsuyuki; Onishi, Takaharu; Tamaru, Kenzi (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (9), 1972)
    The catalytic activities of polynaphthoquinone, containing various metal halides, such as FeCl3, VCl3, MoCl5 and TiCl4, were studied. The polynaphthoquinone was obtained by the oxidation of naphthalene-1,7-diol and successive ...
  • Radiation Chemistry of Butan-l-ol 
    Ackerman, L. G. J; Basson, R. A; Linde, H. J. van der (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    The radiolysis products of butan-l-ol have been determined at low doses. The effects of total energy input, oxygen and ferric chloride on the yields of the products have been studied. The results are interpreted in terms ...
  • Photo-initiation of Polymerization by Manganese(III) Chelates 
    Bamford, C. H; Ferrar, A. N (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    Manganese(lII) acetylacctonatc (Mn(acac)3) and manganese(III) tris(l,l,l-trifluoroacetyl- acetonate) (Mn(facac)3) photosensitize (A = 365 nm) the free-radical polymerization of methyl methacrylate and styrene. Photolysis ...
  • Kinetic Equations for Consecutive Reversible Reactions with Special Reference to Protein Denaturations 
    Hijazi, Nasrat H.; Laidler, Keith J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    The interconversion of the native (N) and denatured (D) form of a protein sometimes exhibits simple exponential kinetic behaviour consistent with the mechanism N⇌D. Sometimes, however, logarithmic plots of the variation ...
  • Light Scattering Studies on n-Dodecyltrimethylammonium Bromide and n-Dodecylpyridinium Iodide 
    Jones, M. N.; Piercy, J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    The aggregation numbers and effective charges of the micelles of n-dodecyltrimethylammonium bromide and n-dodecylpyridinium iodide have been measured over a range of temperature and ionic strength in aqueous solutions by ...
  • Apparent Molar Volumes of Multiply Charged Electrolytes 
    Indelli, A.; Zamboni, R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    The apparent molar volumes of K4Mo(CN)8, K3Cr(C2O4)3, Ca2Fe(CN)6, LaFe(CN)6 and K4Zr(C2O4)4 were measured using a pycnometric and dilatometric methods at 25 and 3.39°C. At 25°C K4Mo(CN)8 follows accurately, K3Cr(C2O4)3 and ...
  • Kinetics of the Reaction between Methyl Iodide and Silver Nitrate in Aqueous Solution 
    Huq, Rokeya (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    The kinetics of the interactions between silver nitrate and methyl iodide in aqueous solution have been followed using a conductivity technique. The observed second-order rate constant increases with initial concentration ...
  • Enthalpy of Solvation of Carbonium Ions 
    Gold, V. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (9), 1972)
    Literature data on the rate of hydrolysis of t-butyl chloride and of the acid-catalyzed hydration of isobutene, both in dilute aqueous solution, have been combined with thermochemical data to yield standard heats of formation ...
  • Kinetics of Reaction of Metal Alkyls with Alkenes: Part 8.—Oligomerization of Ethylene by n-Butyl-lithium- NNN'N'-Tetramethylethylenediamine 
    Hay, J N; McCabe, J F; Robb, J C (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    n-Butyl-lithium (BuLi) in the presence of NNN′N′-tetramethylethylenediamine (TMEDA) progressively adds on ethylene molecules to produce a linear alkyl-lithium compound. This oligomerization has been studied at low pressure, ...
  • Rate of Combination of Trimethylsilyl Radicals in the Gas Phase 
    Cadman, P.; Tilsley, G. M.; Trotman-Dickenson, A. F. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    Trimcthylsilyl radicals have been generated by the mercury photosensitized decomposition of trimcthylsilane. The absolute rate of combination of these radicals has been measured by the classical rotating sector technique ...
  • Dynamic Contact Angles: Part 7.1 Impact Spreading of Water Drops in Air and Aqueous Solutions of Surface Active Agents in Vapour on Smooth Paraffin Wax Surfaces 
    Elliott, T. A.; Ford, D. M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    A drop of pure water impacting on a horizontal solid surface passes through a series of characteristic shapes which are, within specific limits, independent of the height of fall, size of the drop, ambient temperature, and ...
  • E.M.F. Measurements with Solid Electrolyte Galvanic Cells on the Calcium Oxide+Zirconia System: Determination of the Phase Relationships 
    Pizzini, S.; Morlotti, R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (9), 1972)
    E.m.f. measurements on the cell Pt | O2| CaO(+ CaF2)‖ CaF2(tF–= I)‖ ZrO2–CaO | O2| Pt have been carried out in the temperature range 900–1100°C to measure thermodynamic parameters of the lime + zirconia solid solutions ...
  • Specificity in the Interaction between some Chiral Co(III) Complex Ions and DNA in Aqueous Solution 
    Ascoli, F; Branca, M; Mancini, C; Pispisa, B (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    The binding of some chiral Co(IIl) complex ions by native DNA in aqueous solution at pH 7.2 has been studied. Equilibrium dialysis and “ phase-separation ” data show that the affinity for the complex counter-ions used by ...
  • Effects of Salts of Metals on Vinyl Polymerization: Part 8. Polymerization of Vinyl Chloride in the presence of Ferric Chloride 
    Bengough, W. I.; Chawdry, N. M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    The polymerization of vinyl chloride in dimethylformamide, initiated with l,l'-azobisisobutyro- nitrile, and retarded with ferric chloride, has been investigated at temperatures from 40 to 70°C. A 6.65 M monomer concentration ...
  • Kinetic Investigation of the Lanthanide(III)-Nitrate Complexation Reaction 
    Silber, Herbert B; Scheinin, Norman (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    Using ultrasonic relaxation technique the kinetics of lanthanide nitrate complexation were investigated in the presence of excess nitrate ion for Nd(III), Gd(III), Dy(III) and Er(III). The absorption spectra could most ...
  • Contact Angle Studies of Some Low Energy Polymer Surfaces 
    Murphy, W. J.; Roberts, M. W.; Ross, J. R. H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    We have explored the possibility of acquiring information on the molecular nature of some novel polymer films by following Zisman’s approach of determining the critical surface tension yc which is considered to reflect the ...
  • Order-Disorder Transitions at the Liquid/Solid Interface: Volumetric Behaviour of Primary Aliphatic Alcohols near the Graphon Surface 
    Findenegg, G. H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    The volumetric behaviour at the liquid/Graphon interface has been investigated as a function of temperature for the following alcohols in the pure state: hcxan-l-ol (from —38°C to 60°C), and octan-l-ol, decan-l-ol, ...
  • Oxygen Species Adsorbed on Oxides: Part 2.—Formation of (O3X on MgO) 
    Tench, A. J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    MgO surface containing adsorbed (O~)s ions reacts with excess oxygen to form the molecular ion (Oajs- This ion has been characterized by e.s.r. using oxygen enriched with 17O and shows a complex hyperfine structure. Heating ...
  • Oxygen Species Adsorbed on Oxides: Part 1.—Formation and Reactivity of (O_)s on MgO 
    Tench, A. J.; Lawson, T (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    Nitrons oxide reacts with F*(H) centres (surface oxygen ion vacancies with a single trapped electron) to give (O-)/' ions adsorbed at the anion vacancy. The reaction, FS+(H)+N2O ->(O_)t± + N2 is quantitative and the ...
  • Spectral and Energetic Aspects of Water Adsorption by Li-, Na-, K- and Cs-X Zeolites 
    Kiselev, A. V.; Lygin, V. I.; Starodubceva, R. V. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    The infra-red spectra of water adsorbed by X-typc zeolites containing different alkali-metal cations have been studied. With small amounts of adsorption in LiNaX, NaX and KNaX zeolites water molecules interact mainly with ...

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