Journal Articles (before-1995): Recent submissions

  • Effusion-Mass Spectrometric Study of Thermodynamic Properties of Vanadium and Vanadium Nitride 
    Farber, Milton; Srivastava, R. D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (2), 1973)
    Effusion-mass spectrometric studies were performed on the vapour species in equilibrium above VN(c) in the temperature range 1900 to 2412 K. From an analysis of the reactions involved, ΔHf298 values of 122.4 ± 5 kcal/mol ...
  • CO2 poisoning of the γ-alumina-catalyzed reaction of COS with SO2 
    Chuang, T. T.; Lana, I. G. Dalla; Liu, C. L. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3), 1973)
    The poisoning of γ-alumina by CO2 has been shown to suppress the catalytic reaction, 2COS + SO2⇌(3/x)Sx+ 2CO2. Using infra-red spectroscopic evidence, a mechanism of reaction was postulated in which SO2 is adsorbed on ...
  • Enthalpy of Mixing of n-Hexane and Cyclohexane 
    Ahmed, Akhlaq (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (2), 1973)
    The enthalpy of mixing (HE) was measured for the liquids n-hexane and cyclohexane at 298.03 K. HE was corrected to 298.15 K for comparison with the results of other workers. The values of HE are well established with an ...
  • Structure of the Mercury/Ethylene Carbonate Interface: Part 1.—Variation in Double Layer Capacity with the Nature of the Electrolyte 
    Fawcett, W. R.; Mackey, M. D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3), 1973)
    Differential capacity-potential data for the mercury/solution interface for various 1-1 electrolyte solutions in ethylene carbonate at 40°C are presented and compared with data obtained with other aprotic solvents. It is ...
  • Assignment of the Hydroxyl Bands in the Infrared Spectra of Zeolites X and Y: Part 2.—After Different Pretreatments 
    Jacobs, P. A.; Uytterhoeven, J. B. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (2), 1973)
    The i.r. absorption curve of “ deep bed ” calcined NH4Y zeolites could be broken down into the same components as HY zeolites. The frequency of the peaks was slightly changed, but their half band width remained constant. ...
  • Interactions in Lanthanide Systems: Part 2.— Raman Study of Aqueous Cerium(III) Nitrate 
    Nelson, D. L.; Irish, D. E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (1), 1973)
    Raman spectra of aqueous cerium (III) nitrate solutions, and complementary infrared spectra, have been obtained for a wide range of compositions. The intensities of the 718 cm-1 line of solvated nitrate ion have been ...
  • CO2 Poisoning of the ^'-Alumina-catalyzed Reaction of COS with SO2 
    Chuang, T. T.; Lana, I. G. Dalla; Liu, C. L. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3), 1973)
    The isomerization reaction of 3,3-dimcthylbut-l-cnc (1), to produce 2,3-dimcthylbut-l-cnc (11) and 2,3-dimethylbut-2-cne (111), has been investigated over a series of copper-exchanged X-type zeolites. The reaction is ...
  • Assignment of the Hydroxyl Bands in the Infrared Spectra of Zeolites X and Y: Part I.—Na—H Zeolites 
    Jacobs, P. A.; Uytteriioeven, J. B. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (2), 1973)
    The infrared spectra of zeolites X and Y were recorded in the hydroxyl stretching region under high resolution conditions. The samples varied in their Al and proton content. The spectra were broken down into six different ...
  • Hydrogen Bonding in some Adducts of Oxygen Bases with Acids: Part 7.—Thermodynamic Study by Infra-red Spectroscopy of the Association of Chloroacetic Acids with Some Oxygen Bases 
    Hadzi, D.; Rajnvajn, J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (1), 1973)
    The association between the chloroacetic acids (mono-, di-, and tri-) and a scries of bases (dimethyl, dibenzyl, diphenyl sulphoxide, triphenylphosphine oxide, diphenyl selenoxide) in carbon tetrachloride was studied using ...
  • Mechanism of [3-13C]Propene Ammoxidation on Bismuth Molybdate Catalyst 
    Dozono, T.; Thomas, D. W.; Wise, Henry (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3), 1973)
    To study the mechanism of acrylonitrile formation, the ammoxidation of [3-13C]propene was studied in the presence of a bismuth molybdate catalyst on a silica support. The reaction was carried out at 723 K with a conversion ...
  • Heat Capacity of the H2O/KNaX Zeolite Adsorption System 
    Berezin, G. I.; Kiselev, A. V.; Sinitsyn, V. A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3), 1973)
    The heat capacity of the H2O/KNaX zeolite system has been measured at 34°C for various amounts of adsorption. The dependence of measured heat capacity of this system and calculated average molar heat capacity of adsorbate ...
  • Branching Intermediates in the Cool Flames of Acetaldehyde and Simple Ketones 
    Hoare, Derrick E.; Lill, David E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3), 1973)
    Contrary to the postulate of Halstead et al. our work suggests that peracetic acid is not the degenerate branching intermediate in the oxidation of acetaldehyde at temperatures where cool flames occur. It appears that ...
  • Electrons in Liquid Alcohols at Low Temperatures 
    Baxendale, J. H.; Wardman, Peter (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3), 1973)
    The spectra due to electrons in alcohols at temperatures near their melting points show absorptions in the far and infra-red which, in general, decay to produce increased absorptions in the visible. At these temperatures ...
  • Radiolysis of Benzene+Bromobenzene Solutions 
    Kumar, S. S.; Merklin, J. F. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3), 1973)
    Yields of γ-ray radiolysis products from benzene, bromobenzene and solutions of benzene and bromobenzene have been measured. The yield of biphenyl was larger in the solutions than in either of the pure solvents. Rate ...
  • Electron Spin Resonance Study of Intermolecular Cation Exchange Between Sodium Iodide and the Ion Pairs of Sodium Benzophenone and Sodium Naphthalene in Tetrahydrofuran 
    Bailey, J. C.; Colau, P. R.; Warhurst, E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3), 1973)
    Intermolecular cation exchange between sodium iodide and sodium benzophenone and sodium naphthalene ion pairs in THF has been studied by e.s.r. linewidth measurements. For sodium benzophenone the plot of the reciprocal ...
  • Reaction of Hydrogen Atoms with Nitrous Oxide 
    Baldwin, R. R.; Gethin, A.; Walker, R. W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (2), 1973)
    The velocity constant of the reaction H + N2O → N2+ OH (22) has been obtained at 500°C by the addition of N2O to slowly reacting mixtures of H2+ O2+ He and measurement of the relative rates of formation of N2 and H2O. The ...
  • Studies in Ion Solvation in Non-aqueous Solvents and Their Aqueous Mixtures: Part 15.1—Free Energies of Transfer of Cadmium Chloride from Water to 10-40 % (w/w) Methanol-Water Mixtures at 25°C; Dissociation of CdCD; Use of Dilute Cadmium Amalgam Electrodes. The Group II Cations 
    Feakins, D.; Willmott, Alan S.; Willmott, Ann R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (1), 1973)
    The cell Cd(Hg) | CdCl2 | AgCl—Ag has been used to obtain the standard molar free energies of transfer, AGt, of cadmium chloride from water to 10 %, 20 % and 40 % (w/w) mcthanol-water mixtures. Cadmium chloride is a weak ...
  • Temperature Effect on Stearic Acid Monolayers on Water 
    Casilla, R.; Cooper, W. D.; Eley, D. D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (2), 1973)
    Measurements are described for the force-area curve of stearic acid on pure water at temperatures of 1.6, 3.0, 5.0, 10.0 and 20.0°C. The Ao values for both solid and liquid films increase with tempera ture at the same ...
  • Metal-ion Catalyzed Decarboxylation of Oxaloacetic Acid 
    Ito, Hiroo; Kobayashi, Hiroshi; Nomiya, Kenji (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (1), 1973)
    Decarboxylation of oxaloacetic acid is accelerated by hydrated metal ions. The thermodynamic data of activation AG*, AH* and AS* for the rate-determining process were determined. The main species involved in autodecarboxylation ...
  • Heat of Dilution of Aqueous Solutions of Polyacrylates 
    Ise, Norio; Mita, Kazuei; Okubo, Tsuneo (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (1), 1973)
    The heats of dilution (AH) of aqueous solutions of polyacrylates having various gegenions, i.e., sodium and tetra-alkylammonium (alkyl = methyl, ethyl, n-propyl and n-butyl), were measured. The (A//) value of the sodium ...

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