Journal Articles (before-1995): Recent submissions

  • The Oxygen Electrode: Part 3,—Inhibition of the Oxygen Evolution Reaction 
    Burke, L. D.; McCarthy, F.; O’Meara, T. O. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6), 1972)
    The anodic behaviour of water is discussed in terms of a model in which discharge occurs via a cation radical intermediate which rapidly loses a proton to yield potential-determining hydroxyl radicals on the metal surface. ...
  • Thermal Conductivities of Gaseous Mixtures Containing Hydrocarbons: Part 2.—Cyclopropane, Propene, But-l-ene and trans-But-2-ene, and Their Binary Mixtures with Argon 
    Parkinson, C.; Mukhopadhyay, P.; Gray, P. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6), 1972)
    Thermal conductivities of the four pure gases cyclopropane, propene, but-l-ene and trans-but-2- ene and their binary mixtures with argon have been measured at both 50 and 100°C. The thermal conductivities of the pure ...
  • Thermal Conductivities of Gaseous Mixtures Containing Hydrocarbons: Part 1.—n-Butane, iso-Butane, iso-Pentane and neo-Pentane, and Their Binary Mixtures With Argon 
    Parkinson, C.; Gray, P. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6), 1972)
    Thermal conductivities of the four pure gases n-butane, iso-butane, iso-pentanc and nco-pentane and of their binary mixtures with argon have been measured at 50 and 100°C. The thermal conductivities of all four polyatomic ...
  • Vapour-Liquid Equilibrium and Excess Free Energies for Benzene+Dioxan and Carbon Tetrachloride+Dioxan Systems 
    Deshpande, D. D.; Oswal, S. L. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6), 1972)
    This paper deals with the isothermal total vapour pressure measurements on the systems benzene + dioxan and carbon tetrachloride + dioxan in the temperature range of 22-40 'C and over the whole composition range. The ...
  • Excited Singlet and Triplet pK Values of Xanthone in Aqueous Solution 
    Ireland, J. F.; Wyatt, P. A. H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6), 1972)
    Xanthone, which Ikis a ground state pK of -4.1, is shown to have a pK^j) value of +0.96 by fluorescence intensity measurements and a pK(7\) of +3.0 by triplet-triplet absorption measurements. The unusual order pK(7\) ...
  • Sorption of Carboxylate Ions by Strongly Basic Anion Exchangers 
    Gregory, J.; Semmens, M. J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6), 1972)
    Equilibrium data arc reported for the exchange between chloride and a series of carboxylate ions on certain strong-base anion exchange resins. The carboxylates ranged from butyrate to decanoate and, within this range, ...
  • Microwave Absorption in a Helical Polypeptide Molecule 
    Davies, Mansel; Maurel, P.; Price, A. H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6), 1972)
    Microwave absorption measurements (3, 8.5, 36 and 72 GHz) arc reported on three different molecular weight samples of polyCy-bcnzyl-L-glutamatc), PBLG, in two solvents. In each case a distinct absorption, often quite narrow ...
  • Self- and Impurity Diffusion in Anthracene Single Crystals 
    Burns, G.; Sherwood, J. N. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6), 1972)
    A radiotracer study of self- and impurity diffusion in anthracene single crystals of high purity has been made using anthracenc-9-14C, anthraquinone-9-,4C and HO3H as tracers. Lattice self- diffusion is best described by ...
  • Effect of Adsorbed Hydrocarbon on the Catalytic Exchange of n-Butane and Deuterium on Tungsten Films 
    Arroyo, Antonio Cortes; Kemball, C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6), 1972)
    The exchange of n-butane with deuterium is catalyzed by tungsten films at temperatures below 250 K; the reaction involves mainly simple exchange with no evidence of self-poisoning. The adsorption of butane on tungsten at ...
  • Kinetics of ternary complex formation between nickel(II) species and pyridine-2-azo-p-dimethylaniline 
    Cobb, M. A.; Hague, D. N. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    The stopped-flow and temperature-jump relaxation methods have been used to measure the rate constants and activation parameters for the formation and the dissociation of the 1 : 1 complex between nickel(II) and ...
  • Kinetic isotope effects: Part 7.—Ionization of (d)-phenylmethylacetophenone 
    Earls, D. W.; Jones, J. R.; Rumney, T. G. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    Measurements are reported on the hydroxidc-catalyzed ionization of (d)-phenylmethylaceto- phenone in the presence of varying amounts of dimethyl sulphoxide. The kinetic hydrogen isotope effect (kn/kr) increases with ...
  • Adsorption of neopentane on tungsten and palladium films 
    Ross, J. R. H.; Roberts, M. W.; Kemball, C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    The adsorption of neopentane has been studied on tungsten and on palladium films; allied experiments were carried out with methane (W, Pd) and with propane (W). The evolution of hydrogen from each gas/metal system was ...
  • Infra-red studies of rutile surfaces: Part 3.—Adsorption of water and dehydroxylation of rutile 
    Jones, P.; Hockey, J. A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    There are two forms of adsorbed molecular water present on rutile surfaces under ambient conditions. One form is hydrogen bonded to surface hydroxyl ions and the other is held as a coordinating ligand to surface cations.3 ...
  • Infra-red study of the surface properties of rutile: Deuterium exchange, carbon dioxide and but-1-ene adsorption 
    Jackson, P.; Parfitt, G. D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    Deuterium exchange with surface hydroxyl groups on rutile was studied using D2 and D2O; the former completely exchanges at 300°C (2 h) with evidence for surface reduction, while the latter does not achieve complete exchange ...
  • Effect of silica surface dehydroxylation on adsorption of aromatic hydrocarbons from solution in n-alkanes 
    Eltekov, Yu. A.; Khopina, V. V.; Kiselev, A. V. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    The adsorption of a series of aromatic hydrocarbons from solution in saturated hydrocarbons on hydroxylated and dehydroxylated silica surface has been investigated. Dehydroxylation of silica surface sharply diminishes the ...
  • Reactions of trifluoromethyl radicals with organic halides: Part 7.—Chloro- and fluorochloro-ethanes 
    Quick, L. M.; Whittle, E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    The reactions of CF3 radicals with the compounds C2H5Cl, CH2ClCH2Cl, CH3CHCl2, CH3CCl3, CHCl2CHCl2, CF3CH2Cl, CF3CHCl2, CF3CCl3, CF2ClCFCl2 and CH3CF2Cl were studied. Arrhenius parameters were measured for abstraction of ...
  • Reactions of CF3 radicals with benzotrifluoride and the C—H bond strength in C6H5CF3 and C6H6 
    Bérces, T.; Márta, F.; Szilágyi, I. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    The reactions of CF3 with benzotrifluoride (BTF) were studied at 1029, 1070 and 1132 K. The RCF3H/R½C2F6[BTF] ratio was found to decrease with increasing benzotrifluoride pressure, which was interpreted as simultaneous ...
  • Electrical Conductance in Molten KC1, KI, TH and KI-TII 
    Buckle, E. R.; Tsaoussoglou, P. E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6), 1972)
    Specific conductance, x, in the ionic melts KC1, KI, Til and KI-T1I was measured by the a.c.- dispersion plateau method. The variation of z with temperature (T, C) in the pure melts is given to 0.1 % by empirical equations ...
  • Reactions of Group 3 Metal Alkyls in the Gas Phase: Part 9.—Addition of Propene to Trimethylaluminium 
    Egger, Kurt W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6), 1972)
    The thermal gas phase reaction of propene with monomeric trimethylaluminium has been studied at temperatures from 455 to 549 K using a static reaction system and Teflon coated reaction vessels. Initial propene pressures ...
  • Liquid State Thermal Conductivity of n-Paraffin Hydrocarbons 
    Kandiyoti, R.; McLaughlin, E.; Pittman, J. F. T. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    New measurements on the thermal conductivities of n-butane, n-pentane, n-heptane and n-octane in the liquid state at saturation pressure are reported. The results are discussed in terms of the dependence of thermal ...

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