Rate of Combination of Trimethylsilyl Radicals in the Gas Phase

Cadman, P.; Tilsley, G. M.; Trotman-Dickenson, A. F.

dc.contributor.author	Cadman, P.
dc.contributor.author	Tilsley, G. M.
dc.contributor.author	Trotman-Dickenson, A. F.
dc.date.accessioned	2025-01-31T05:59:03Z
dc.date.available	2025-01-31T05:59:03Z
dc.date.issued	1972
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/16956
dc.description.abstract	Trimcthylsilyl radicals have been generated by the mercury photosensitized decomposition of trimcthylsilane. The absolute rate of combination of these radicals has been measured by the classical rotating sector technique between 317 and 399 K, using the abstraction of chlorine from ethyl chloride to give chlorotrimcthylsilane as the pilot reaction. The activation energy for combination was found to be negligible and the rate coefficient to be given by: log (K/ml mol~l s-1) = 14.25±0.30 where the error is estimated from the experimental scatter.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10)	en_US
dc.subject	Chemistry	en_US
dc.subject	Trimethylsilyl Radicals	en_US
dc.subject	Mercury Photosensitized	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Rate of Combination of Trimethylsilyl Radicals in the Gas Phase	en_US
dc.type	Article	en_US