Addition of Formaldehyde to Slowly Reacting Hydrogen + Oxygen Mixtures

Baldwin, R R; Fuller, A R; Walker, R W

dc.contributor.author	Baldwin, R R
dc.contributor.author	Fuller, A R
dc.contributor.author	Walker, R W
dc.date.accessioned	2025-01-31T11:32:28Z
dc.date.available	2025-01-31T11:32:28Z
dc.date.issued	1972
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17001
dc.description.abstract	The effect of HCHO in reducing the induction periods of H2+ O2+ N2 mixtures at 500°C has been examined for a range of mixture composition, using HCHO concentrations in the range 0.05–1.0 %. Computer treatment shows that the marked reduction can only be accounted for by the reaction HO2+ HCHO = H2O2+ HCO(24). A detailed computer analysis of the results for a range of mixtures gives the ratio k24/k½10= 23 (mol l.–1 s)–½. Taking k10(HO2+ HO2= H2O2+ O2)= 1.8 × 109 gives k24= 9.6 × 105 l.mol–1 s–1. With A24= 109, this corresponds to E24= 10.7 kcal mol–1.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7)	en_US
dc.subject	Chemistry	en_US
dc.subject	Formaldehyde	en_US
dc.subject	Hydrogen	en_US
dc.subject	Oxygen Mixtures	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Addition of Formaldehyde to Slowly Reacting Hydrogen + Oxygen Mixtures	en_US
dc.type	Article	en_US