Reactions of Cyanogen Radicals: Part 3.—Arrhenius Parameters for Reactions with Alkanes

Bullock, G. E.; Cooper, R.

dc.contributor.author	Bullock, G. E.
dc.contributor.author	Cooper, R.
dc.date.accessioned	2025-02-03T06:41:52Z
dc.date.available	2025-02-03T06:41:52Z
dc.date.issued	1972
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17035
dc.description.abstract	Using the technique of gas phase pulse radiolysis, the Arrhenius parameters for the reactions of CN radicals with methane and ethane have been determined. With methane there is an activation energy of 8.3 6± 0.5 kJ mol-1 whereas for the reaction with ethane the value is 0(<800) J mol-1. Also reported are the rate constants at 300 K for reaction with CD4 and propane. The effects of vibrational excitation of the CN radicals on the apparent rate constants is discussed.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (12)	en_US
dc.subject	Chemistry	en_US
dc.subject	Reactions of Cyanogen	en_US
dc.subject	Radicals	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Reactions of Cyanogen Radicals: Part 3.—Arrhenius Parameters for Reactions with Alkanes	en_US
dc.type	Article	en_US