Thermal Decomposition of Ethyl, Isopropyl and t-Butyl  Fluorides in the Gas Phase

Dastoor, P. N.; Emovon, E. U.

dc.contributor.author	Dastoor, P. N.
dc.contributor.author	Emovon, E. U.
dc.date.accessioned	2025-02-03T11:56:03Z
dc.date.available	2025-02-03T11:56:03Z
dc.date.issued	1972
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17109
dc.description.abstract	Ethyl, isopropyl and t-butyl fluorides decompose in a flow system into hydrogen fluoride and the corresponding olefin by a predominantly molecular mechanism. The first order rate constants are given by the Arrhenius equations: ethyl fluoride (520–600°C) : k/s–1= 1012.16±0.04exp–59 200±2000/RT, isopropyl fluoride(445–522°C) : k/s–1= 1011.83±0.02 exp–53 900±800/RT, t-butyl fluoride (329–370°C) : k/s–1= 1013.96±0.01 exp–50 400±900/RT.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11)	en_US
dc.subject	Chemistry	en_US
dc.subject	Thermal Decomposition	en_US
dc.subject	Alkyl Fluorides	en_US
dc.subject	Gas-Phase Reactions	en_US
dc.subject	Reaction Kinetics	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Thermal Decomposition of Ethyl, Isopropyl and t-Butyl Fluorides in the Gas Phase	en_US
dc.type	Article	en_US