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Reactions of the HO2 Radical in Aqueous Solution with Bromine and Related Compounds

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dc.contributor.author Sutton, H C
dc.contributor.author Downes, M T
dc.date.accessioned 2025-02-03T11:57:31Z
dc.date.available 2025-02-03T11:57:31Z
dc.date.issued 1972
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17122
dc.description.abstract A flow system has been used to produce HO2 in concentrations up to 38 µM by the radiolysis of oxygen saturated aqueous formate solutions. Rate constants for the following reactions have been obtained by competitive studies, relative to the known rate of reaction of O–2 with tetranitromethane: HO2+ Br2→ H++ O2+ Br–2k=(1.1+0.6–0.4)× 108 M–1 s–1, O–2+ Br2→ O2+ Br–2k=(5.6 ± 0.7)× 109 M–1 s–1, HO2+ Br–3→ H++ O2+ Br–+ Br–2k < 107 M–1 s–1, O–2+ Br–3→ O2+ Br–+ Br–2k=(3.8 ± 0.7)× 109 M–1 s–1, O–2+ HOBr → OH–+ O2+ Br k=(9.5 ± 0.8)× 108 M–1 s–1 en_US
dc.language.iso en en_US
dc.publisher Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (8) en_US
dc.subject Chemistry en_US
dc.subject HO2 en_US
dc.subject Aqueous Solution en_US
dc.subject Bromine en_US
dc.subject Journal of the Chemical Society : Faraday Transaction - I en_US
dc.title Reactions of the HO2 Radical in Aqueous Solution with Bromine and Related Compounds en_US
dc.type Article en_US


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