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Lattice Defects in Plastic Organic Crystals: Part 7.—Isotope Mass Effects in Self-diffusion in Cyclohexane

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dc.contributor.author Chadwick, A. V.
dc.contributor.author Sherwood, J. N.
dc.date.accessioned 2025-02-04T14:34:36Z
dc.date.available 2025-02-04T14:34:36Z
dc.date.issued 1972
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17163
dc.description.abstract A study has been made of the diffusion of the species 12C514C11H12 and 12C62H113H1 in single crystals of cyclohexane at 242 K. The measured diffusion coefficients are in good agreement with previously published values. An estimate of the isotope mass effect yields a value of the mass factor Eab= 0.003 ± 0.004. This virtually-zero value indicates that self-diffusion in cyclohexane proceeds by a complicated mechanism in which many molecules are involved ( >12). This discovery confirms previous speculations on the defect structure of the low entropy of fusion plastic solids. en_US
dc.language.iso en en_US
dc.publisher Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (1) en_US
dc.subject Chemistry en_US
dc.subject Lattice Defects en_US
dc.subject Plastic Organic Crystals en_US
dc.subject Isotope Mass Effects en_US
dc.subject Self-Diffusion in Cyclohexane en_US
dc.subject Journal of the Chemical Society : Faraday Transaction - I en_US
dc.title Lattice Defects in Plastic Organic Crystals: Part 7.—Isotope Mass Effects in Self-diffusion in Cyclohexane en_US
dc.type Article en_US


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