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Standard Potentials of Silver/Silver Halide Electrodes and Ion Solvation in Glycerol+Water Mixtures at 25°C

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dc.contributor.author Khoo, K. H.
dc.date.accessioned 2025-02-04T14:38:27Z
dc.date.available 2025-02-04T14:38:27Z
dc.date.issued 1972
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17198
dc.description.abstract Standard e.m.f. of the cells H2/HX/AgX—Ag (X = Cl, Br, or I) in 10, 20, 30, 40, 50 and 70 % (w/w) glycerol H- water mixtures at 25°C arc reported. Consideration of the molar free energies of transfer of the proton and halide ions from water to the mixed solvents leads to the view that glycerol is more “ basic ” than water. The solvation effect opposes but predominates over the electrostatic efiect in the transfer of the proton to the mixed solvents. In the transfer of anions, the solvation effect reinforces the electrostatic effect resulting in large positive values of the transfer free energy. en_US
dc.language.iso en en_US
dc.publisher Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (3) en_US
dc.subject Chemistry en_US
dc.subject Halide Electrodes en_US
dc.subject Ion Solvation en_US
dc.subject Journal of the Chemical Society : Faraday Transaction - I en_US
dc.title Standard Potentials of Silver/Silver Halide Electrodes and Ion Solvation in Glycerol+Water Mixtures at 25°C en_US
dc.type Article en_US


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