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Electron Spin Resonance Studies of Photo-Oxidation by Metal Ions in Rigid Media at Low Temperatures: Part 3.—Ce(lV) Photo-Oxidations of Aldehydes, Ketones, Esters and Amides

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dc.contributor.author Greatorex, D.
dc.contributor.author Kemp, T. J.
dc.date.accessioned 2025-02-05T15:04:10Z
dc.date.available 2025-02-05T15:04:10Z
dc.date.issued 1972
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17228
dc.description.abstract A survey is presented of the primary processes in the photo-oxidation by Ce(IV) ions at 77 K of a variety of organic molecules classified by functional group; these processes have been determined by characterization of the resulting organic free radical by electron spin resonance spectroscopy. Aldehydes RCHO and aldehyde hydrates RCH(OH)2 are oxidized to RĊO and RĊC(OH)2 respectively, although C2H5ĊO disappears at 120 K, producing instead CH3ĊHCHO. Ketones produce either the alkyl radical R from RCOR′ or the radical derived by abstraction of a hydrogen atom from the methylene or methine groups adjacent to the carbonyl group; in some cases both types of radical are discernible. Esters also undergo C—H or C—C fission processes depending on the degree of substitution of the R fragment of RCO2R′, whilst formamide yields a spectrum of ·CONH2. Methyl methacrylate yields a vinylic monomer radical at 77 K which induces polymerization at 175 K to give the polymethyl methacrylate radical. en_US
dc.language.iso en en_US
dc.publisher Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (1) en_US
dc.subject Chemistry en_US
dc.subject Electron Spin Resonance en_US
dc.subject Photo-Oxidation en_US
dc.subject Cerium(IV) en_US
dc.subject Aldehydes, Ketones, Esters, and Amides en_US
dc.subject Journal of the Chemical Society : Faraday Transaction - I en_US
dc.title Electron Spin Resonance Studies of Photo-Oxidation by Metal Ions in Rigid Media at Low Temperatures: Part 3.—Ce(lV) Photo-Oxidations of Aldehydes, Ketones, Esters and Amides en_US
dc.type Article en_US


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