dc.contributor.author |
Cobb, M. A. |
|
dc.contributor.author |
Hague, D. N. |
|
dc.date.accessioned |
2025-02-08T02:46:41Z |
|
dc.date.available |
2025-02-08T02:46:41Z |
|
dc.date.issued |
1972 |
|
dc.identifier.uri |
http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17387 |
|
dc.description.abstract |
The stopped-flow and temperature-jump relaxation methods have been used to measure the rate constants and activation parameters for the formation and the dissociation of the 1 : 1 complex between nickel(II) and pyridine-2-azo-p-dimethylaniline (PADA) and of the ternary complexes between PADA and the nickel(II)-polytriphosphate, -iminodiacetate, -N-methyliminodiacetate, -nitrilotriacetate, -diethylenetriamine, -triethylenetetramine and -2,2′,2″-triaminotriethylamine complexes. The rate constants at 25°C for the reaction between the Ni(II) complex of 1,4,8,11-tetra-azaundecane(2,3,2-tet) and NH3 are also reported. The series provides further evidence that the number of binding nitrogen atoms on the first ligand has a larger influence on ternary complex formation than its charge. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5) |
en_US |
dc.subject |
Chemistry |
en_US |
dc.subject |
Kinetics |
en_US |
dc.subject |
Ternary Complex Formation |
en_US |
dc.subject |
Nickel(II) Species |
en_US |
dc.subject |
Pyridine-2-azo-p-dimethylaniline |
en_US |
dc.subject |
Journal of the Chemical Society : Faraday Transaction - I |
en_US |
dc.title |
Kinetics of ternary complex formation between nickel(II) species and pyridine-2-azo-p-dimethylaniline |
en_US |
dc.type |
Article |
en_US |