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Kinetics of ternary complex formation between nickel(II) species and pyridine-2-azo-p-dimethylaniline

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dc.contributor.author Cobb, M. A.
dc.contributor.author Hague, D. N.
dc.date.accessioned 2025-02-08T02:46:41Z
dc.date.available 2025-02-08T02:46:41Z
dc.date.issued 1972
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17387
dc.description.abstract The stopped-flow and temperature-jump relaxation methods have been used to measure the rate constants and activation parameters for the formation and the dissociation of the 1 : 1 complex between nickel(II) and pyridine-2-azo-p-dimethylaniline (PADA) and of the ternary complexes between PADA and the nickel(II)-polytriphosphate, -iminodiacetate, -N-methyliminodiacetate, -nitrilotriacetate, -diethylenetriamine, -triethylenetetramine and -2,2′,2″-triaminotriethylamine complexes. The rate constants at 25°C for the reaction between the Ni(II) complex of 1,4,8,11-tetra-azaundecane(2,3,2-tet) and NH3 are also reported. The series provides further evidence that the number of binding nitrogen atoms on the first ligand has a larger influence on ternary complex formation than its charge. en_US
dc.language.iso en en_US
dc.publisher Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5) en_US
dc.subject Chemistry en_US
dc.subject Kinetics en_US
dc.subject Ternary Complex Formation en_US
dc.subject Nickel(II) Species en_US
dc.subject Pyridine-2-azo-p-dimethylaniline en_US
dc.subject Journal of the Chemical Society : Faraday Transaction - I en_US
dc.title Kinetics of ternary complex formation between nickel(II) species and pyridine-2-azo-p-dimethylaniline en_US
dc.type Article en_US


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