dc.contributor.author |
Arroyo, Antonio Cortes |
|
dc.contributor.author |
Kemball, C. |
|
dc.date.accessioned |
2025-02-08T02:46:48Z |
|
dc.date.available |
2025-02-08T02:46:48Z |
|
dc.date.issued |
1972 |
|
dc.identifier.uri |
http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17388 |
|
dc.description.abstract |
The exchange of n-butane with deuterium is catalyzed by tungsten films at temperatures below 250 K; the reaction involves mainly simple exchange with no evidence of self-poisoning. The adsorption of butane on tungsten at temperatures from 273 to 423 K gives strongly adsorbed hydrocarbon species which reduce the rate of the subsequent exchange at 273 K by factors of from 10 to 2000, the effect increasing with the adsorption temperature. Only a fraction of these adsorbed species is easily rehydrogenated. Some results for comparison arc obtained with adsorbed but-l-ene, neopentane or methane. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6) |
en_US |
dc.subject |
Chemistry |
en_US |
dc.subject |
Adsorbed Hydrocarbon |
en_US |
dc.subject |
Catalytic Exchange |
en_US |
dc.subject |
Journal of the Chemical Society : Faraday Transaction - I |
en_US |
dc.title |
Effect of Adsorbed Hydrocarbon on the Catalytic Exchange of n-Butane and Deuterium on Tungsten Films |
en_US |
dc.type |
Article |
en_US |