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Effect of Adsorbed Hydrocarbon on the Catalytic Exchange of n-Butane and Deuterium on Tungsten Films

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dc.contributor.author Arroyo, Antonio Cortes
dc.contributor.author Kemball, C.
dc.date.accessioned 2025-02-08T02:46:48Z
dc.date.available 2025-02-08T02:46:48Z
dc.date.issued 1972
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17388
dc.description.abstract The exchange of n-butane with deuterium is catalyzed by tungsten films at temperatures below 250 K; the reaction involves mainly simple exchange with no evidence of self-poisoning. The adsorption of butane on tungsten at temperatures from 273 to 423 K gives strongly adsorbed hydrocarbon species which reduce the rate of the subsequent exchange at 273 K by factors of from 10 to 2000, the effect increasing with the adsorption temperature. Only a fraction of these adsorbed species is easily rehydrogenated. Some results for comparison arc obtained with adsorbed but-l-ene, neopentane or methane. en_US
dc.language.iso en en_US
dc.publisher Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6) en_US
dc.subject Chemistry en_US
dc.subject Adsorbed Hydrocarbon en_US
dc.subject Catalytic Exchange en_US
dc.subject Journal of the Chemical Society : Faraday Transaction - I en_US
dc.title Effect of Adsorbed Hydrocarbon on the Catalytic Exchange of n-Butane and Deuterium on Tungsten Films en_US
dc.type Article en_US


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