Effect of Adsorbed Hydrocarbon on the Catalytic Exchange of n-Butane and Deuterium on Tungsten Films

Arroyo, Antonio Cortes; Kemball, C.

dc.contributor.author	Arroyo, Antonio Cortes
dc.contributor.author	Kemball, C.
dc.date.accessioned	2025-02-08T02:46:48Z
dc.date.available	2025-02-08T02:46:48Z
dc.date.issued	1972
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17388
dc.description.abstract	The exchange of n-butane with deuterium is catalyzed by tungsten films at temperatures below 250 K; the reaction involves mainly simple exchange with no evidence of self-poisoning. The adsorption of butane on tungsten at temperatures from 273 to 423 K gives strongly adsorbed hydrocarbon species which reduce the rate of the subsequent exchange at 273 K by factors of from 10 to 2000, the effect increasing with the adsorption temperature. Only a fraction of these adsorbed species is easily rehydrogenated. Some results for comparison arc obtained with adsorbed but-l-ene, neopentane or methane.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6)	en_US
dc.subject	Chemistry	en_US
dc.subject	Adsorbed Hydrocarbon	en_US
dc.subject	Catalytic Exchange	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Effect of Adsorbed Hydrocarbon on the Catalytic Exchange of n-Butane and Deuterium on Tungsten Films	en_US
dc.type	Article	en_US