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Vapour-Liquid Equilibrium and Excess Free Energies for Benzene+Dioxan and Carbon Tetrachloride+Dioxan Systems

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dc.contributor.author Deshpande, D. D.
dc.contributor.author Oswal, S. L.
dc.date.accessioned 2025-02-08T02:47:17Z
dc.date.available 2025-02-08T02:47:17Z
dc.date.issued 1972
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17393
dc.description.abstract This paper deals with the isothermal total vapour pressure measurements on the systems benzene + dioxan and carbon tetrachloride + dioxan in the temperature range of 22-40 'C and over the whole composition range. The activity coefficients and the excess Gibbs free energies arc evaluated at 25, 30 and 40'C. For both the systems the excess entropies arc negative, suggesting an ordering in the solution due to a solute-solvent specific interaction. The excess free energies of complexing arc calculated on the basis of an ideal associated solution model with species A, B, AB and AB2 in mutual equilibrium and using for reference, the excess free energies of the system cyclohexane 4- dioxan. The calculated excess free energies agree with the observed results. en_US
dc.language.iso en en_US
dc.publisher Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6) en_US
dc.subject Chemistry en_US
dc.subject Liquid Equilibrium en_US
dc.subject Carbon Tetrachloride en_US
dc.subject Journal of the Chemical Society : Faraday Transaction - I en_US
dc.title Vapour-Liquid Equilibrium and Excess Free Energies for Benzene+Dioxan and Carbon Tetrachloride+Dioxan Systems en_US
dc.type Article en_US


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