Kinetic Hydrogen Isotope Effect in the Fluorination of H2, CH4 and CHCI3

Foon, Ruby; Reid, G. P.; Tait, K. B.

dc.contributor.author	Foon, Ruby
dc.contributor.author	Reid, G. P.
dc.contributor.author	Tait, K. B.
dc.date.accessioned	2025-02-08T02:48:04Z
dc.date.available	2025-02-08T02:48:04Z
dc.date.issued	1972
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17401
dc.description.abstract	Kinetic isotope effects for the hydrogen abstraction reactions of fluorine atoms with H2, CH and CHC13 have been measured by indirect competitive methods. The relative rate constants arc given by, The result for A(H2)/A(D2) agrees with that previously measured. These relatively small kinetic isotope effects are compared with rate parameters calculated from activated complex theory and classical trajectory analysis. Hydrogen atom transfer by quantum mechanical tunnelling is apparently unimportant.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6)	en_US
dc.subject	Chemistry	en_US
dc.subject	Hydrogen Isotope	en_US
dc.subject	Fluorination	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Kinetic Hydrogen Isotope Effect in the Fluorination of H2, CH4 and CHCI3	en_US
dc.type	Article	en_US