dc.contributor.author |
Whytock, D A |
|
dc.date.accessioned |
2025-02-08T05:15:02Z |
|
dc.date.available |
2025-02-08T05:15:02Z |
|
dc.date.issued |
1972 |
|
dc.identifier.uri |
http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17412 |
|
dc.description.abstract |
The reactions of C2F5 radicals with neopentane and propane have been studied, using perfluoroethyl iodide as the free radical source. The Arrhenius parameters, based on A= 1013.36 cm3 mol–1 s–1 and E= 0 for the combination of C2F5 radicals, are: [graphic omitted] Analysis of the propyl iodides in the products allows calculation of the Arrhenius parameters for C2F5 attack at specific sites in the propane molecule, providing the values: [graphic omitted] Arrhenius parameters for hydrogen abstraction from alkanes by C2F5, CF3 and C2H5 radicals are compared; C2H5 is the least reactive whilst CF3 and C2F5 have similar reactivities. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (4) |
en_US |
dc.subject |
Chemistry |
en_US |
dc.subject |
Perfluoroethyl Radicals |
en_US |
dc.subject |
Propane |
en_US |
dc.subject |
Neopentane |
en_US |
dc.subject |
Journal of the Chemical Society : Faraday Transaction - I |
en_US |
dc.title |
Reactions of Perfluoroethyl Radicals with Propane and Neopentane |
en_US |
dc.type |
Article |
en_US |