Excited Products in the Photodissociation of Methyl Thiocyanate  and Isothiocyanate in the Vacuum Ultra-violet

D’Amario, P.; Stefano, G. Di; Lenzi, M.; Mele, A.

dc.contributor.author	D’Amario, P.
dc.contributor.author	Stefano, G. Di
dc.contributor.author	Lenzi, M.
dc.contributor.author	Mele, A.
dc.date.accessioned	2025-02-10T15:15:34Z
dc.date.available	2025-02-10T15:15:34Z
dc.date.issued	1972
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17451
dc.description.abstract	Photolysis of CH3NCS and CH3SCN in the vacuum u.-v. produces fluorescence attributed to SCN excited radicals. In the case of CH3SCN production of CNB2∑+ system is also found. The threshold wavelength of incident photons for SCN formation is 197 ± 1 nm for CH3SCN and 188 ± 1 nm for CH3NCS. These values give D(CH3—SCN)= 3.04 eV and D(CH3—NCS)= 3.37 eV for the production of NCSA2Πi. A value of ΔHf(SCN)= 3.19 eV (76.4 kcal mol–1) has been calculated.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5)	en_US
dc.subject	Chemistry	en_US
dc.subject	Photodissociation	en_US
dc.subject	Methyl Thiocyanate and Isothiocyanate	en_US
dc.subject	Vacuum Ultraviolet (VUV) Radiation	en_US
dc.subject	Excited Products	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Excited Products in the Photodissociation of Methyl Thiocyanate and Isothiocyanate in the Vacuum Ultra-violet	en_US
dc.type	Article	en_US