Interactions in Lanthanide Systems: Part 2.— Raman Study of Aqueous Cerium(III) Nitrate

Nelson, D. L.; Irish, D. E.

dc.contributor.author	Nelson, D. L.
dc.contributor.author	Irish, D. E.
dc.date.accessioned	2025-02-11T07:17:42Z
dc.date.available	2025-02-11T07:17:42Z
dc.date.issued	1973
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17479
dc.description.abstract	Raman spectra of aqueous cerium (III) nitrate solutions, and complementary infrared spectra, have been obtained for a wide range of compositions. The intensities of the 718 cm-1 line of solvated nitrate ion have been measured and used to evaluate the average ligand number h. The data yield stability constants B1 = 1.68 and B2= 1.17 for Ce(NO3)2+ and CefNOj). Spectral features suggest that the most prevalent structure of the dinitratocerium(III) species involves one nitrate ion bound in monodentate fashion and one nitrate ion bound in bidentatc fashion. Band assignments are suggested for the nitrate ligands assuming C2, symmetry.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (1)	en_US
dc.subject	Chemistry	en_US
dc.subject	Lanthanide Systems	en_US
dc.subject	Raman Study	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Interactions in Lanthanide Systems: Part 2.— Raman Study of Aqueous Cerium(III) Nitrate	en_US
dc.type	Article	en_US