CO2 poisoning of the γ-alumina-catalyzed reaction of COS with SO2

Chuang, T. T.; Lana, I. G. Dalla; Liu, C. L.

dc.contributor.author	Chuang, T. T.
dc.contributor.author	Lana, I. G. Dalla
dc.contributor.author	Liu, C. L.
dc.date.accessioned	2025-02-11T07:18:11Z
dc.date.available	2025-02-11T07:18:11Z
dc.date.issued	1973
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17483
dc.description.abstract	The poisoning of γ-alumina by CO2 has been shown to suppress the catalytic reaction, 2COS + SO2⇌(3/x)Sx+ 2CO2. Using infra-red spectroscopic evidence, a mechanism of reaction was postulated in which SO2 is adsorbed on hydroxyl sites and COS is adsorbed on aluminum ion sites. The latter sites become blocked through irreversible chemisorption of CO2. The postulated mechanism appears to explain other experimental observations.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3)	en_US
dc.subject	Chemistry	en_US
dc.subject	CO2 Poisoning	en_US
dc.subject	γ-alumina	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	CO2 poisoning of the γ-alumina-catalyzed reaction of COS with SO2	en_US
dc.type	Article	en_US