Kinetics and Thermodynamics of the Proton-transfer  Reactions of 2,4-Dinitrophenol with some Amine Bases in  Chlorobenzene studied by a Microwave Temperature-jump  Method

Caldin, Edward F.; Crooks, John E.; Donnell, Derek O’

dc.contributor.author	Caldin, Edward F.
dc.contributor.author	Crooks, John E.
dc.contributor.author	Donnell, Derek O’
dc.date.accessioned	2025-02-12T05:08:48Z
dc.date.available	2025-02-12T05:08:48Z
dc.date.issued	1973
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17560
dc.description.abstract	The proton-transfer reactions of 2,4-dinitrophenol with trimethylamine, tri-n-octylamine, quinuclidine and triethylenediamine in chlorobenzene at 25CC have been studied. Equilibrium constants have been determined spectrophotometrically, and rate constants for some of the reactions have been determined by means of a microwave temperature-jump apparatus. The forward rate constants are one-tenth to one-hundredth of the value calculated for diffusion control. They do not correlate with the equilibrium constants, but appear to be related to steric factors.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (6)	en_US
dc.subject	Chemistry	en_US
dc.subject	Proton-Transfer Reactions	en_US
dc.subject	Kinetics	en_US
dc.subject	Thermodynamics	en_US
dc.subject	Microwave Temperature-Jump Method	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Kinetics and Thermodynamics of the Proton-transfer Reactions of 2,4-Dinitrophenol with some Amine Bases in Chlorobenzene studied by a Microwave Temperature-jump Method	en_US
dc.type	Article	en_US