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Microwave Spectroscopic Studies of Hydrogen Exchange, Isomerization and Hydrogenation of Unsaturated Hydrocarbons on the Stoichiometric Electron Donor-Acceptor Complexes of Phthalocyanine with Alkali Metals

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dc.contributor.author Naito, Shuichi
dc.contributor.author Ichikawa, Masaru
dc.contributor.author Saito, Shuji
dc.date.accessioned 2025-02-12T05:50:32Z
dc.date.available 2025-02-12T05:50:32Z
dc.date.issued 1973
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17563
dc.description.abstract Hydrogen exchange, isomerization and hydrogenation of olefins, such as C2H4, C3H6 and C4H8, was studied over the stoichiometric electron donor–acceptor (EDA) complexes of various phthalocyanines with alkali metals (Li, Na, K). The mass and microwave spectroscopic techniques have been shown to be effective for determining not only the deuterium content but also its distribution in the [2H1] and [2H2]-species of the reactant and product molecules. It was accordingly concluded that these three reactions proceed through the same reaction intermediate; the half-hydrogenated state of the olefins, and that the rate-determining step is the process where the π-coordinated olefin becomes the σ-coordinated half-hydrogenated state. The chemisorbed state of the olefins and the mechanisms of these reactions were correlated with the electron configuration of the EDA complexes. en_US
dc.language.iso en en_US
dc.publisher Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (4) en_US
dc.subject Chemistry en_US
dc.subject Microwave Spectroscopy en_US
dc.subject Phthalocyanine Complexes en_US
dc.subject Journal of the Chemical Society : Faraday Transaction - I en_US
dc.title Microwave Spectroscopic Studies of Hydrogen Exchange, Isomerization and Hydrogenation of Unsaturated Hydrocarbons on the Stoichiometric Electron Donor-Acceptor Complexes of Phthalocyanine with Alkali Metals en_US
dc.type Article en_US


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