Semiquinone Free Radicals and Oxygen: Pulse Radiolysis Study of One Electron Transfer Equilibria

Patel, Kantilal B.; Willson, Robin L.

dc.contributor.author	Patel, Kantilal B.
dc.contributor.author	Willson, Robin L.
dc.date.accessioned	2025-02-12T06:59:09Z
dc.date.available	2025-02-12T06:59:09Z
dc.date.issued	1973
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17596
dc.description.abstract	The absorption characteristics and acid dissociation constants of the semiquinone radicals of several methyl derivatives of benzoquinone and naphthoquinone have been determined by pulse radiolysis. Absolute rate constants for electron transfer from the superoxide-ion O–2 to mono- and di-methyl benzoquinones have been determined. In the case of duroquinone, evidence has been obtained for the occurrence of the equilibrium reaction: O–2+ duroquinone ⇌ O2+ durosemiquinone with Kc= 2.3 ± 0.2 × 10–2.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (4)	en_US
dc.subject	Chemistry	en_US
dc.subject	Pulse Radiolysis	en_US
dc.subject	Electron Transfer Equilibria	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Semiquinone Free Radicals and Oxygen: Pulse Radiolysis Study of One Electron Transfer Equilibria	en_US
dc.type	Article	en_US