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Stability Constants of Some Complexes of t-Butyl Mesityl Nitroxide

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dc.contributor.author Burnett, George M.
dc.contributor.author Cameron, G. Gordon
dc.contributor.author Cameron, James
dc.date.accessioned 2025-02-13T05:21:16Z
dc.date.available 2025-02-13T05:21:16Z
dc.date.issued 1973
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17649
dc.description.abstract Stability constants for complex formation of t-butyl mesityl nitroxide with various solvents and monomers have been determined in the range 25-85 C by gas-liquid chromatography and a spectrophotometric method. In general, molecules with extensive conjugation form the most stable complexes but diethyl malonate provides a notable exception. Solvents which form the most stable complexes show the strongest effects on the rate coefficients of propagation in radical polymerization of methyl methacrylate and styrene. This correlation supports the view that a proportion of the active macroradicals are complexed with monomer or solvent. en_US
dc.language.iso en en_US
dc.publisher Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (5) en_US
dc.subject Chemistry en_US
dc.subject Cameron en_US
dc.subject t-Butyl Mesityl Nitroxide en_US
dc.subject Journal of the Chemical Society : Faraday Transaction - I en_US
dc.title Stability Constants of Some Complexes of t-Butyl Mesityl Nitroxide en_US
dc.type Article en_US


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