Kinetics of the Proton-transfer Reactions between  2,4-Dinitrophenol and Tertiary Amines: Possible Influence of Rotation in the Encounter Complex

Ivin, Kenneth J.; McGarvey, John J.; Simmons, Eugene L.; Small, Raymond

dc.contributor.author	Ivin, Kenneth J.
dc.contributor.author	McGarvey, John J.
dc.contributor.author	Simmons, Eugene L.
dc.contributor.author	Small, Raymond
dc.date.accessioned	2025-02-13T05:42:39Z
dc.date.available	2025-02-13T05:42:39Z
dc.date.issued	1973
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17655
dc.description.abstract	Kinetic and equilibrium data are reported for the proton-transfer reactions in chlorobenzene between 2,4-dinitrophenol and triethylamine, tri-n-propylamine, tri-n-pentylamine, tri-n-nonylamine and triethylenediamine. The forward rate constants are a factor of 5-35 below the limit predicted by simple diffusion theory. These results are interpreted by means of a theory which takes account of rotation of the reactants within the encounter complex during the period of an encounter.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (6)	en_US
dc.subject	Chemistry	en_US
dc.subject	Kinetics	en_US
dc.subject	Proton-transfer Reactions	en_US
dc.subject	2,4-Dinitrophenol	en_US
dc.subject	Tertiary Amines	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Kinetics of the Proton-transfer Reactions between 2,4-Dinitrophenol and Tertiary Amines: Possible Influence of Rotation in the Encounter Complex	en_US
dc.type	Article	en_US