Abstraction of Chlorine Atoms from Alkyl Chlorides by the Trimethylsilyl Radical

Cadman, P.; Tilsley, G. M.; Dickenson, A. F. Trotman

dc.contributor.author	Cadman, P.
dc.contributor.author	Tilsley, G. M.
dc.contributor.author	Dickenson, A. F. Trotman
dc.date.accessioned	2025-02-13T06:08:22Z
dc.date.available	2025-02-13T06:08:22Z
dc.date.issued	1973
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17664
dc.description.abstract	The relative rates of chlorine atom abstraction from alkyl chlorides by the trimethylsilyl radical have been studied by a competitive technique between 400 and 580 K in the gas phase. These results have been put on an absolute basis by comparing the rate of abstraction of chlorine from ethyl chloride by trimethylsilyl radicals with their rate of combination to hexamethyldisilane. Using the known rate of combination of trimethylsilyl radicals, the following Arrhenius parameters for chlorine abstraction were obtained: [graphic omitted] The results of the chlorine abstractions by the trimethylsilyl radicals are compared with those for sodium atoms and for trichlorosilyl radicals.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (5)	en_US
dc.subject	Chemistry	en_US
dc.subject	Abstraction	en_US
dc.subject	Chlorine Atoms	en_US
dc.subject	Alkyl Chlorides	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Abstraction of Chlorine Atoms from Alkyl Chlorides by the Trimethylsilyl Radical	en_US
dc.type	Article	en_US