Structure of the Mercury/Ethylene Carbonate Interface:  Part 3.—Adsorption of Thiourea

Fawcett, W. R.; Mackey, M. D.

dc.contributor.author	Fawcett, W. R.
dc.contributor.author	Mackey, M. D.
dc.date.accessioned	2025-02-14T11:06:12Z
dc.date.available	2025-02-14T11:06:12Z
dc.date.issued	1974
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17738
dc.description.abstract	The adsorption of thiourea at mercury from ethylene carbonate solutions containing 0.5 mol dm–3 KPF6 and varying amounts of thiourea has been studied by measuring the differential capacity of the polarisable interface as a function of potential. The data were analysed to obtain the surface excess of thiourea as a function of electrode potential and bulk concentration. The parameters characterising the adsorption isotherm are discussed in terms of the electrostatic model for dipole adsorption by Kir'yanov, Krylov and Damaskin. These parameters are also compared with those obtained previously for the adsorption of thiourea from water, methanol, formamide, and dimethylformamide.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6)	en_US
dc.subject	Chemistry	en_US
dc.subject	Mercury/Ethylene Carbonate	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Structure of the Mercury/Ethylene Carbonate Interface: Part 3.—Adsorption of Thiourea	en_US
dc.type	Article	en_US