Electron Spin Resonance Detection of Radical Intermediates During Photo-oxidation by Metal Ions in Solution

Greatorex, David; Hill, Richard J.; Kemp, Terence J.; Stone, Thomas J.

dc.contributor.author	Greatorex, David
dc.contributor.author	Hill, Richard J.
dc.contributor.author	Kemp, Terence J.
dc.contributor.author	Stone, Thomas J.
dc.date.accessioned	2025-02-17T11:14:52Z
dc.date.available	2025-02-17T11:14:52Z
dc.date.issued	1974
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17834
dc.description.abstract	Irradiation of fluid solutions of ceric and uranyl ions in various organic media in the temperature range 140–290 K gives rise in many cases to well-resolved e.s.r. spectra of solvent-derived radicals, enabling characterisation of the photolytic process. Whilst UO2+2 photo-oxidises predominantly, but not exclusively, by means of abstracting a hydrogen atom from carbon adjacent to an activating site such as —OH or —CO2H, Ce(IV) attacks by a process of C—C fission; for example RCO2H yields R˙ and R′CH2OH yields, not R′ĊHOH as is customarily found at 77 K, but R′˙.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6)	en_US
dc.subject	Chemistry	en_US
dc.subject	Electron Spin Resonance Detection	en_US
dc.subject	Photo-oxidation	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Electron Spin Resonance Detection of Radical Intermediates During Photo-oxidation by Metal Ions in Solution	en_US
dc.type	Article	en_US