Kinetics and Mechanism of the Reduction of Manganese(III) in Perchloric Acid at a Platinum Electrode

Rosseinsky, David R.; Hill, R. John

dc.contributor.author	Rosseinsky, David R.
dc.contributor.author	Hill, R. John
dc.date.accessioned	2025-02-17T11:17:12Z
dc.date.available	2025-02-17T11:17:12Z
dc.date.issued	1974
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17836
dc.description.abstract	The electrode kinetics at 25°C of the reduction of manganese(III) on an oxidised platinum surface confirms an unusually low transfer coefficient of 0.26. Interpretation involving a comparison with a correlation of hydrolytic constants of similar trivalent cations and their several redox potentials points to a hydroxo- or oxo-bridged transition state. The MnHi/Mn11 conditional standard electrode potential was observed to be 1.535 V at ionic strength 3.31 mol dm-3 against H2\|HC1O4(3 mol dm-3), NaClO4 (0.31 mol dm-3).	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6)	en_US
dc.subject	Chemistry	en_US
dc.subject	Kinetics	en_US
dc.subject	Manganese(III)	en_US
dc.subject	Platinum Electrode	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Kinetics and Mechanism of the Reduction of Manganese(III) in Perchloric Acid at a Platinum Electrode	en_US
dc.type	Article	en_US