DSpace Repository

Ionic Conduction in Ammonium Perchlorate Doped with Divalent Ions

Show simple item record

dc.contributor.author Owen, Gari P.
dc.contributor.author Thomas, John M.
dc.contributor.author Williams, John O.
dc.date.accessioned 2025-02-18T11:03:54Z
dc.date.available 2025-02-18T11:03:54Z
dc.date.issued 1974
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17862
dc.description.abstract D.c. electrical measurements are reported for sulphate-ion-doped and barium-ion-doped ammonium perchlorate. The extension of an impurity-dominated regime in sulphate-ion-doped ammonium perchlorate, and the fact that barium-ion-doped ammonium perchlorate displays no marked difference in electrical behaviour from that of the “pure” salt strongly suggests that the conduction process in ammonium perchlorate is controlled by interstitial ammonium ions. Measurements of surface conduction reveal no evidence for proton conduction at or near the surface where such a process would be expected to dominate via sublimation. The dominant point defect structure deduced from electrical measurements, i.e. interstitial NH+4 ions would seem to favour electron transfer from ClO–4 to NH+4 ions as the first step in the thermal decomposition of the solid, since this mechanism requires the existence of interstitial NH+4 ions. en_US
dc.language.iso en en_US
dc.publisher Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11) en_US
dc.subject Chemistry en_US
dc.subject Ionic Conduction en_US
dc.subject Divalent Ions en_US
dc.subject Ammonium Perchlorate en_US
dc.subject Journal of the Chemical Society : Faraday Transaction - I en_US
dc.title Ionic Conduction in Ammonium Perchlorate Doped with Divalent Ions en_US
dc.type Article en_US


Files in this item

This item appears in the following Collection(s)

Show simple item record

Search DSpace


Advanced Search

Browse

My Account