Mass Spectrometric Determination of the Dissociation Energies of the Molecules CuLi, AgLi and AuLi

Neubert, A.; Zmbov, K. F.

dc.contributor.author	Neubert, A.
dc.contributor.author	Zmbov, K. F.
dc.date.accessioned	2025-02-19T11:40:41Z
dc.date.available	2025-02-19T11:40:41Z
dc.date.issued	1974
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17909
dc.description.abstract	Equilibria involving gaseous species CuLi, AgLi and AuLi have been investigated using a Knudsen effusion technique combined with mass spectrometric analysis of the vapour composition. The following dissociation energies were derived by the third law procedure from the measured ion intensities, free energy functions and auxiliary data: D°0(CuLi)= 189.3 ± 8.8 kJ mol–1, D°0(AgLi)= 173.6 ± 6.3 kJ mol–1, D°0(AuLi)= 280.8 ± 6.5 kJ mol–1. The measured dissociation energies are considerably lower than those calculated from the Pauling model of the polar bond.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (12)	en_US
dc.subject	Chemistry	en_US
dc.subject	Spectrometric Determination	en_US
dc.subject	Dissociation Energies	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Mass Spectrometric Determination of the Dissociation Energies of the Molecules CuLi, AgLi and AuLi	en_US
dc.type	Article	en_US