Kinetics of the reaction of the nickel(II) ion with pyridine-2-azo-p-dimethylaniline in t-butanol + water mixtures

Caldin, Edward F.; Godfrey, Peter

dc.contributor.author	Caldin, Edward F.
dc.contributor.author	Godfrey, Peter
dc.date.accessioned	2025-02-19T11:50:52Z
dc.date.available	2025-02-19T11:50:52Z
dc.date.issued	1974
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17914
dc.description.abstract	Rate constants and activation parameters have been determined for the reaction of the nickel(II) ion with pyridine -2-azo-p-dimethylaniline, in a series of t-butanol + water mixtures with mole fractions from 0 to 0.4 t-butanol. The rate constant at 25°C varies little with composition, but the enthalpy and entropy of activation both vary considerably, with compensation; they show maxima and minima, which are discussed in relation to theories of solvent structure.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (12)	en_US
dc.subject	Chemistry	en_US
dc.subject	Reactions	en_US
dc.subject	Kinetics	en_US
dc.subject	Nickel Ion	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Kinetics of the reaction of the nickel(II) ion with pyridine-2-azo-p-dimethylaniline in t-butanol + water mixtures	en_US
dc.type	Article	en_US