Solutal Marangoni augmented levitation time of an aqueous surfactant drop over an immiscible oil pool

Abstract

Droplets are found to exhibit a finite residence time over the volatile liquid pool due to the confined evaporation mediated sustained thin film draining. The levitated drops are quite critical in biomedical applications such as for the biophysical micro reactors. It is hypothesized that the presence of surfactants can induce solutal Marangoni and can further enhance the levitation time. Moreover, the surfactant drops can closely mimic the bio drop assay. Droplets of surfactant solutions are allowed to impact over a series of volatile hydrocarbon oils to understand the effect of surfactant concentration, impact height and the properties of the oil pool using high speed imaging technique. Flow visualization is employed in the pendant droplet mode to understand the Marangoni induced internal circulation. The droplets of surfactant solutions are found to exhibit enhanced residence time compared to the case of non-surfactant drops. The levitation time is a function of the surfactant concentration and the volatility of the oil pool. A mathematical model is developed incorporating the effect of solutal Marangoni to test the hypothesis and is found to predict the levitation time with reasonable accuracy. A universal floating–sinking regime map was developed incorporating the influence of governing parameters.