Nuclear magnetic resonance studies of preferential solvation: Part 3.—Thermodynamic treatment involving change of solvation number, and application to dimethyl sulphoxide-containing solvents

Covington, Arthur K.; Lantzke, Ian R.; Thain, Jennifer M.

dc.contributor.author	Covington, Arthur K.
dc.contributor.author	Lantzke, Ian R.
dc.contributor.author	Thain, Jennifer M.
dc.date.accessioned	2025-03-07T10:40:08Z
dc.date.available	2025-03-07T10:40:08Z
dc.date.issued	1974
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18202
dc.description.abstract	Studies of 7Li and 133Cs ion n.m.r. chemical shifts in dimethyl sulphoxide (DMSO)+ water mixtures, have been interpreted in terms of a series of competitive equilibria in which the solvation number of the ions for DMSO is half that for water. It is concluded that nitrate ions are preferentially solvated by DMSO and Li+ by water. The treatment has also been applied to 133Cs shift data for sulpholan and water mixtures, and it is concluded that caesium ions are solvated by the organic component.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10)	en_US
dc.subject	Chemistry	en_US
dc.subject	Nuclear Magnetic Resonance (NMR) Spectroscopy	en_US
dc.subject	Preferential Solvation	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Nuclear magnetic resonance studies of preferential solvation: Part 3.—Thermodynamic treatment involving change of solvation number, and application to dimethyl sulphoxide-containing solvents	en_US
dc.type	Article	en_US