Photoinduced oxidation of propan-2-ol by acid chromate

Kläning, Ulrik K.

dc.contributor.author	Kläning, Ulrik K.
dc.date.accessioned	2025-03-10T05:30:01Z
dc.date.available	2025-03-10T05:30:01Z
dc.date.issued	1977
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18214
dc.description.abstract	The photoinduced oxidation of propan-2-ol by acid chromate has been studied (i) by flash photolysis, (ii) by quantum yield measurements at low light intensity, (iii) by e.s.r. measurements during photolysis of solutions containing a spin trap, and (iv) by e.s.r. measurements of glassy samples photolysed at –165°C. It was found that CrIV is formed in the primary processes, the most efficient of which involves the ester of acid chromate. The rate of formation of the ester was measured. A mechanism for the subsequent reactions of CrIV is given. In general the reactions of CrIV with another CrIV or with CrV are fast compared with the reaction of CrIV with propan-2-ol in the formation of 2-hydroxypropyl radicals. The reaction of CrIV with CrVI is immeasurably slow.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (03)	en_US
dc.subject	Chemistry	en_US
dc.subject	acid chromate	en_US
dc.subject	Photoinduced oxidation	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Photoinduced oxidation of propan-2-ol by acid chromate	en_US
dc.type	Article	en_US