dc.contributor.author |
Freiberg, Mira |
|
dc.contributor.author |
Meyerstein, Dan |
|
dc.date.accessioned |
2025-03-10T11:00:39Z |
|
dc.date.available |
2025-03-10T11:00:39Z |
|
dc.date.issued |
1977 |
|
dc.identifier.uri |
http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18253 |
|
dc.description.abstract |
The effect of CdSO4 and NiSO4 on the radiolytic hydrogen yield and its isotopic composition in the systems H2O + CH3OH, H2O + CD3OH, D2O + CH3OD, H2O +(CH3)2CHOH, H2O +(CH3)2 CDOH and D2O +(CH3)2CHOD are reported.
The results suggest that hydrogen atoms and aliphatic radicals oxidize Cd+aq and Ni+aq. Furthermore it is suggested that the reaction Cd—C(CH3)2 OH+→ CdH++(CH3)[graphic omitted] occurs in aqueous solutions. The implications of these observations on earlier results are discussed. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04) |
en_US |
dc.subject |
Chemistry |
en_US |
dc.subject |
hydrogen atoms |
en_US |
dc.subject |
aliphatic radicals |
en_US |
dc.subject |
Journal of the Chemical Society : Faraday Transaction - I |
en_US |
dc.subject |
monovalent cadmium |
en_US |
dc.subject |
radiation chemical systems |
en_US |
dc.title |
Reactions of hydrogen atoms and aliphatic radicals with monovalent cadmium and nickel ions as a source of hydrogen yield in some radiation chemical systems |
en_US |
dc.type |
Article |
en_US |