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Reactions of hydrogen atoms and aliphatic radicals with monovalent cadmium and nickel ions as a source of hydrogen yield in some radiation chemical systems

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dc.contributor.author Freiberg, Mira
dc.contributor.author Meyerstein, Dan
dc.date.accessioned 2025-03-10T11:00:39Z
dc.date.available 2025-03-10T11:00:39Z
dc.date.issued 1977
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18253
dc.description.abstract The effect of CdSO4 and NiSO4 on the radiolytic hydrogen yield and its isotopic composition in the systems H2O + CH3OH, H2O + CD3OH, D2O + CH3OD, H2O +(CH3)2CHOH, H2O +(CH3)2 CDOH and D2O +(CH3)2CHOD are reported. The results suggest that hydrogen atoms and aliphatic radicals oxidize Cd+aq and Ni+aq. Furthermore it is suggested that the reaction Cd—C(CH3)2 OH+→ CdH++(CH3)[graphic omitted] occurs in aqueous solutions. The implications of these observations on earlier results are discussed. en_US
dc.language.iso en en_US
dc.publisher Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04) en_US
dc.subject Chemistry en_US
dc.subject hydrogen atoms en_US
dc.subject aliphatic radicals en_US
dc.subject Journal of the Chemical Society : Faraday Transaction - I en_US
dc.subject monovalent cadmium en_US
dc.subject radiation chemical systems en_US
dc.title Reactions of hydrogen atoms and aliphatic radicals with monovalent cadmium and nickel ions as a source of hydrogen yield in some radiation chemical systems en_US
dc.type Article en_US


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