Kinetics of Methylene Addition to cis- and r/w?s-But-2-ene: Further Evidence for the Energy Separation between Triplet and Singlet Methylene

Frey, Henry M; Kennedy, Gordon J.

dc.contributor.author	Frey, Henry M
dc.contributor.author	Kennedy, Gordon J.
dc.date.accessioned	2025-04-07T06:31:08Z
dc.date.available	2025-04-07T06:31:08Z
dc.date.issued	1977
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18558
dc.description.abstract	The reactions of triplet and singlet methylene with cis- and trans-but-2-ene have been studied over the temperature range 350–473 K. The results yield a value of (36.5 ± 3.2) kJ mol–1 for the energy separation between singlet and triplet methylene, and provide further confirmation of the assumption that singlet methylene reactions with hydrocarbons proceed with activation energies close to zero. Previous evidence for the similar reactivities of triplet methylene and the methyl radical receives additional support.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (1)	en_US
dc.subject	Chemistry	en_US
dc.subject	Kinetics	en_US
dc.subject	Methylene	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Kinetics of Methylene Addition to cis- and r/w?s-But-2-ene: Further Evidence for the Energy Separation between Triplet and Singlet Methylene	en_US
dc.type	Article	en_US