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Thermodynamic Study of Deuterium Exchange in Water-;-Methanol Systems

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dc.contributor.author Fenby, David V.
dc.date.accessioned 2025-04-25T10:59:47Z
dc.date.available 2025-04-25T10:59:47Z
dc.date.issued 1978
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18799
dc.description.abstract Molar excess enthalpies are reported for the systems H2O + CH3OH, H2O + CH3OD, H2O + CD3OD, D2O + CH3OH, D2O + CH3OD and D2O + CD3OD at 298.15 K. The results are analysed to give the enthalpies of the deuterium exchange reactions CH3OH(l)+ HDO(l)= CH3OD(l)+ H2O(l) and CH3OH(l)+ D2O(l)= CH3OD(l)+ HDO(l). A new analysis of previously published partial molar enthalpies of solution gives enthalpies of reaction in good agreement with those obtained from our excess enthalpy results. These calorimetric values are in striking disagreement with statistical mechanical enthalpies of reaction. en_US
dc.language.iso en en_US
dc.publisher Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07) en_US
dc.subject Chemistry en_US
dc.subject Thermodynamic study en_US
dc.subject Water-methanol systems en_US
dc.subject Journal of the Chemical Society : Faraday Transaction - I en_US
dc.title Thermodynamic Study of Deuterium Exchange in Water-;-Methanol Systems en_US
dc.type Article en_US


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