Nuclear Magnetic Relaxation Studies of Preferential Solvation in Electrolyte Solutions

Capparelli, Alberto L.; Gill, Dip S.; Hertz, H. Gerhard; Tutsch, Rüdiger; Weingärtner, Hermann

dc.contributor.author	Capparelli, Alberto L.
dc.contributor.author	Gill, Dip S.
dc.contributor.author	Hertz, H. Gerhard
dc.contributor.author	Tutsch, Rüdiger
dc.contributor.author	Weingärtner, Hermann
dc.date.accessioned	2025-04-28T09:06:42Z
dc.date.available	2025-04-28T09:06:42Z
dc.date.issued	1978
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18811
dc.description.abstract	Formulae are derived which describe the increase in the total proton magnetic relaxation rate relative to the intramolecular relaxation rate in a solvent mixture when solvent molecules of one kind are enriched in the solvation sphere of a dissolved ion. Experimental nuclear magnetic relaxation results regarding the application of these formulae for solutions of Mg(ClO4)2, KI and RbI in water + methanol mixtures are reported. It is shown that preferential solvation effects are present in these systems, they are ascribed to preferential hydration of the cations.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07)	en_US
dc.subject	Chemistry	en_US
dc.subject	Nuclear magnetic relaxation	en_US
dc.subject	Solvent–solvent interactions	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Nuclear Magnetic Relaxation Studies of Preferential Solvation in Electrolyte Solutions	en_US
dc.type	Article	en_US