Structural Analysis of Some Molten Materials by X-ray Diffraction Part 5.—LiCl, PbCL and their Mixtures

Ohno, Hideo; Yoroki, Mitsugu; Furukawa, Kazuo; Takagi, Yoshiki; Nakamura, Tetsuro

dc.contributor.author	Ohno, Hideo
dc.contributor.author	Yoroki, Mitsugu
dc.contributor.author	Furukawa, Kazuo
dc.contributor.author	Takagi, Yoshiki
dc.contributor.author	Nakamura, Tetsuro
dc.date.accessioned	2025-04-28T09:23:29Z
dc.date.available	2025-04-28T09:23:29Z
dc.date.issued	1978
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18813
dc.description.abstract	The molten structure of PbCl2, LiCl and their mixtures were examined by X-ray diffraction analysis. In molten Pbcl2, each Pb atom is surrounded by about eight Cl atoms at a distance of 2.92 Å, which is near to the sum of the ionic radii of Pb2+ and Cl–. It is expected that only very few rigid complex anions will be present in molten PbCl2. The results of X-ray diffraction analysis in molten PbCl2 are consistent with those of Raman spectroscopy. The average Pb–Pb interaction in the molten state should be intermediate between a b.c.c. and an s.c. arrangement and the s.c. arrangement takes precedence with increasing LiCl concentration.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07)	en_US
dc.subject	Chemistry	en_US
dc.subject	Structural analysis	en_US
dc.subject	Molten materials	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Structural Analysis of Some Molten Materials by X-ray Diffraction Part 5.—LiCl, PbCL and their Mixtures	en_US
dc.type	Article	en_US