On the Hydrolysis of Agn, T1H, Sn111 and CuI[1

Asmus, Klaus-Dieter; Toffel, Peter; Bonifacio, Marija

dc.contributor.author	Asmus, Klaus-Dieter
dc.contributor.author	Toffel, Peter
dc.contributor.author	Bonifacio, Marija
dc.date.accessioned	2025-05-06T11:09:34Z
dc.date.available	2025-05-06T11:09:34Z
dc.date.issued	1978
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18861
dc.description.abstract	Using pulse radiolysis with optical, conductometric and polarographic detection it is shown that the oxidation of T1+, Ag+, Cu2 ! and Sn2 ■ by hydroxyl radicals proceeds via on OH adduct: Mc"+ + •OH Me(OH)'l+. Depending on pH, the OH adduct may react with a proton followed by water elimination, may add OH- or react with water followed by elimination of a proton. The pA" values for the equilibria Me('l+‘)+ = Mc(OH)n+ ~ Me(OH)O-1)4 decrease with increasing state of oxidation of Me. The oxidative properties decrease with increasing state of hydrolysis.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08)	en_US
dc.subject	Chemistry	en_US
dc.subject	Hydrolysis	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	On the Hydrolysis of Agn, T1H, Sn111 and CuI[1	en_US
dc.type	Article	en_US