Self-reactions of Isopropylperoxy Radicals in the Gas Phase

Kirsch, Leslie J.; Parkes, David A.; Waddington, David J.; Woolley, Allan

dc.contributor.author	Kirsch, Leslie J.
dc.contributor.author	Parkes, David A.
dc.contributor.author	Waddington, David J.
dc.contributor.author	Woolley, Allan
dc.date.accessioned	2025-05-09T09:23:18Z
dc.date.available	2025-05-09T09:23:18Z
dc.date.issued	1978
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18899
dc.description.abstract	The photo-oxidation of 2,2′-azopropane has been studied in order to determine the overall rate constant for the second-order removal of isopropylperoxy radicals. Arrhenius parameters of log10(Aobs/dm3 mol–1 s–1)= 9.15 ± 0.03 and Eobs= 18.65 ± 0.50 kJ mol–1 have been determined over a temperature range 300–373 K. These values are compared with those obtained for the self-reactions of primary and tertiary alkylperoxyradicals, and the corresponding reactions in solution.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12)	en_US
dc.subject	Chemistry	en_US
dc.subject	Isopropylperoxy radical	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Self-reactions of Isopropylperoxy Radicals in the Gas Phase	en_US
dc.type	Article	en_US