Reactions of Alkyl Radicals with Nitrogen Trifluoride

Cadman, Philip; Inel, Yuksel; Trotman-Dickenson, Aubrey F.

dc.contributor.author	Cadman, Philip
dc.contributor.author	Inel, Yuksel
dc.contributor.author	Trotman-Dickenson, Aubrey F.
dc.date.accessioned	2025-05-09T09:36:03Z
dc.date.available	2025-05-09T09:36:03Z
dc.date.issued	1978
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18900
dc.description.abstract	Photolysis of mixtures of nitrogen trifluoride with the appropriate ketones (in the temperature range 303–486 K) has enabled the reactions of CH3, CF3, C2H5, i-C3H7 and t-C4H9 radicals with nitrogen trifluoride to be studied. With the smaller radicals only the abstraction of difluoroamino radicals is important, but with i-C3H7 and t-butyl both difluoroamino and fluorine abstraction occur. The Arrhenius parameters are given. The disproportionation—combination ratio for methyl and t-butyl radicals was found to be 0.83 ± 0.02.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12)	en_US
dc.subject	Chemistry	en_US
dc.subject	Nitrogen trifluoride	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Reactions of Alkyl Radicals with Nitrogen Trifluoride	en_US
dc.type	Article	en_US