Kinetics of the Thermal Isomerisation of Hexamethyldisilane

Davidson, Iain M. T.

dc.contributor.author	Davidson, Iain M. T.
dc.date.accessioned	2025-06-23T11:01:20Z
dc.date.available	2025-06-23T11:01:20Z
dc.date.issued	1974
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18967
dc.description.abstract	A kinetic investigation of the gas-phase isomerisation of hexamethyldisilane between 717 and 780 K with initial pressures of 10-125 mmHg is described, and discussed in relation to other work on the thermolysis of hexamethyldisilane. The isomerisation is a radical chain reaction of three halves order, with rate constants given by Xr/cmJ moH s-' = iol6-6s±o-7O exp[— (251 ± 8)/2?T] (activation energy in kJ mol-1).	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6)	en_US
dc.subject	Chemistry	en_US
dc.subject	Kinetics	en_US
dc.subject	Hexamethyldisilane	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Kinetics of the Thermal Isomerisation of Hexamethyldisilane	en_US
dc.type	Article	en_US