dc.contributor.author |
Primet, Michel |
|
dc.contributor.author |
Basset, Jean-Marie |
|
dc.contributor.author |
Mathieu, Michel-Vital |
|
dc.date.accessioned |
2025-06-23T11:14:22Z |
|
dc.date.available |
2025-06-23T11:14:22Z |
|
dc.date.issued |
1974 |
|
dc.identifier.uri |
http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18973 |
|
dc.description.abstract |
Of the various forms of hydrogen adsorbed on platinum only hydrogen weakly and reversibly
adsorbed is detected by an infra-red band at 2120 cm-1. The preparation of a well dispersed sample
of Pt/ALO? catalyst containing 10 % platinum allows us to determine accurately the hydrogen
adsorption isotherm of this weakly adsorbed species. Only a dissociative Langmuir model fits the
experimental results in the pressure range of 10'1 to 700 Torr and temperature range of 27 to 95°C.
The heat of adsorption (—5 x 104 J mol-1) and the isosteric heat of adsorption are in good agree
ment with previous calorimetric data. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6) |
en_US |
dc.subject |
Chemistry |
en_US |
dc.subject |
Infra-red Determination |
en_US |
dc.subject |
Isotherm of Hydrogen Adsorption |
en_US |
dc.subject |
Journal of the Chemical Society : Faraday Transaction - I |
en_US |
dc.title |
Infra-red Determination of the Isotherm of Hydrogen Adsorption on a Pt/Al2O3 Catalyst |
en_US |
dc.type |
Article |
en_US |