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Poisoning of a Supported Molybdenum Olefin Disproportionation Catalyst

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dc.contributor.author Howe, Russell F.
dc.contributor.author Kemball, Charles
dc.date.accessioned 2025-06-24T09:53:25Z
dc.date.available 2025-06-24T09:53:25Z
dc.date.issued 1974
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18990
dc.description.abstract Nitric oxide and carbon monoxide have been used to poison a propene disproportionation catalyst prepared from molybdenum hexacarbonyl on silica. Nitric oxide is strongly adsorbed, and an effective poison, but infra-red spectra indicate that adsorption occurs on more than one type of site, so that estimates of the active sites obtained are upper limits only. The nitric oxide poisoning experiments have shown that molybdenum is well dispersed on the silica support. Carbon monoxide is not strongly adsorbed; the slight poisoning effect observed can be accounted for in terms of competition between gas phase carbon monoxide and propene for the active sites. en_US
dc.language.iso en en_US
dc.publisher Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07) en_US
dc.subject Chemistry en_US
dc.subject Molybdenum Olefin en_US
dc.subject Disproportionation Catalyst en_US
dc.subject Journal of the Chemical Society : Faraday Transaction - I en_US
dc.title Poisoning of a Supported Molybdenum Olefin Disproportionation Catalyst en_US
dc.type Article en_US


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