On reaction of 2,2′-bipyridine with iridium(III), an “aggregation induced phosphorescence (AIP)” active “rollover” complex, [Ir(PPh3)2(bipy-H)(Cl)(H)] (bipy-H = κ2-N,C-2,2′-bipyridine) or [Ir(bipy-H)], is obtained. The ...

In the last decades, compounds with ‘Aggregation-Induced Emission’ (AIE), which are weakly or non-emissive at all in solution but exhibit a strong luminescence in aggregated states, have emerged as an extraordinary ...

The article reports a straightforward strategy for the design and synthesis of highly luminescent conjugated mesoporous oligomers (CMOs) with an “aggregation-induced enhanced emission” (AIEE) feature through Wittig ...

Four new Ir(III) complexes with the general formula [IrHCl(C^N)(PPh3)2] containing different conjugated Schiff base ligands (C^N) have been synthesized and characterized by 1H, 13C, and 31P NMR, HRMS, and IR spectra and ...

Luminescent materials have great potential in diverse applications in their solid state. Because these materials are subject to the aggregation-caused quenching (ACQ) effect, increasing attention is focused on synthesizing ...

In this article, we tried to redefine the unexplored potential of a benzothiazole type of Schiff-base (OM), which was identified as an AIE-active molecule that exhibits excited-state intramolecular proton transfer (ESIPT). ...

Typical aggregation-induced emission (AIE) luminogens tetraphenylethylene (TPE) and triphenylamine have been used to construct an AIE-active conjugated polymer, namely, poly(N,N-diphenyl-4-(4-(1,2,2-triphenylvinyl)styryl)aniline) ...

The brown nitro isomer, trans-[NiL2(NO2)2], 1 (L = N,N′-dipropyl-1,2-diaminoethane), was synthesized by adding L to a suspension of K4[Ni(NO2)6]·H2O in methanol. Complex 1 is metastable at ca. 298 K and transforms slowly ...

One new two-dimensional and two one-dimensional organic/inorganic composite coordination polymers have been synthesised by the reaction of cadmium(II) halides with N-(3-hydroxypropyl)ethane-1,2-diamine (L) and structurally ...

A greenish-blue emissive bis-cyclometalated iridium(III) complex with octahedral geometry was synthesized in a convenient route where a bulky substituted ligand, N1-tritylethane-1,2-diamine ligand (trityl-based rotating ...